Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate (CAS: 80049-61-2) is a ruthenium-based organometallic compound with the formula [(C5H5)Ru(CH3CN)3]PF6 and a molecular weight of 434.28 g/mol. It is primarily employed as a catalyst in various organic synthesis reactions, demonstrating utility in allylation, O-H insertion, hydrosilylation, and rearrangement processes. This compound is supplied by Tech Serve Solutions for research and development purposes.
- IUPAC
- (Cyclopentadienyltris(acetonitrile)ruthenium hexafluorophosphate,Tris(acetonitrile)cyclopentadienylruthenium hexafluorophosphate
![Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate ([(C5H5)Ru(CH3CN)3]PF6) — chemical structure, CAS 80049-61-2; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F80049-61-2.png&w=3840&q=75)
Dehydrative Allylation Catalyst
This compound acts as a catalyst for the regioselective and stereoselective dehydrative allylation of nucleophiles. It facilitates the introduction of allyl groups under mild conditions.
O-H Insertion and Condensation Reactions
It is effective in catalysing O-H insertion and condensation reactions. This enables the formation of new carbon-oxygen bonds and facilitates condensation processes in organic synthesis.
Hydrosilylation
Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate catalyses hydrosilylation reactions. This process is crucial for the synthesis of organosilicon compounds.
Decarboxylative Allylic Etherification
The compound is employed in decarboxylative allylic etherification. This reaction offers a pathway for creating allylic ethers through the removal of a carboxyl group.
Claisen Rearrangement
It catalyses the Claisen rearrangement of unactivated allyl vinyl ethers. This rearrangement is a fundamental tool for carbon-carbon bond formation.
| Molecular weight | 434.28 |
|---|---|
| Linear formula | [(C5H5)Ru(CH3CN)3]PF6 |
| Storage temperature | 2-8°C |
| Application | Catalyst for:• Regioselective and stereoselective dehydrative allylation of nucleophiles1• O-H Insertion and condensation reactions2• Hydrosilylation3,4• Decarboxylative allylic etherification5• Claisen rearrangement of unactivated allyl vinyl ethers6 |
Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate used for?
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Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate is primarily used as a catalyst in various organic synthesis reactions, including dehydrative allylation, O-H insertion, condensation reactions, hydrosilylation, decarboxylative allylic etherification, and Claisen rearrangements.
What is the CAS number and formula for this compound?
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The CAS number is 80049-61-2, and the chemical formula is [(C5H5)Ru(CH3CN)3]PF6.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this compound for research and development purposes. The specific grade and purity are available upon request. Tech Serve Solutions does not represent this product as USP, BP, or EP grade.
What are the safety and handling precautions for this chemical?
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This compound is classified as a Warning with hazards H315 (Causes skin irritation), H319 (Causes serious eye irritation), and H335 (May cause respiratory irritation). It is recommended to wear a dust mask type N95 (US), eyeshields, and gloves. Ensure adequate ventilation.
How is Tris(acetonitrile)cyclopentadienylruthenium(II) hexafluorophosphate packed and shipped?
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This chemical is typically stored at 2-8°C. It is carefully packed and exported by Tech Serve Solutions to meet international shipping regulations for chemical compounds.
How can I request a sample or a quote for this product?
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You can request a sample or a quote by contacting the Tech Serve Solutions sales team directly through our website or by calling us. Please provide the product name and CAS number.
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