Methylhydrazine
Methylhydrazine (CAS 60-34-4), a volatile and flammable liquid with the molecular formula CH3NHNH2 and a molar mass of 46.07 g/mol, is a key organic building block. It is primarily recognised for its reactivity as a strong reducing agent and nucleophile. This compound finds significant application in chemical synthesis, particularly in the production of various organic intermediates and specialised chemicals.
- IUPAC
- MMH

Chemical Synthesis
Methylhydrazine serves as a versatile reagent in organic synthesis, enabling the formation of diverse heterocyclic compounds and nitrogen-containing molecules. Its nucleophilic character makes it valuable for introducing hydrazine functionalities into organic structures.
Rocket Propellant Component
Historically, methylhydrazine has been investigated and used as a component in hypergolic rocket propellants due to its high energy density and rapid ignition characteristics when combined with oxidisers.
Precursor for Organic Intermediates
It acts as a precursor in the synthesis of pharmaceuticals, agrochemicals, and dyes, where the hydrazine moiety is incorporated into more complex molecular architectures.
| Molecular weight | 46.07 |
|---|---|
| Linear formula | CH3NHNH2 |
| Assay | ≥98.0% (GC) |
| Boiling point | 88-90 °C(lit.) |
| Density | 0.875 g/mL at 20 °C(lit.) |
| Refractive index | n20/D 1.4325(lit.)n20/D 1.434 |
| Vapour pressure | 37.5 mmHg (20 °C) |
| Vapour density | 1.6 (vs air) |
| Autoignition temp | 385 °F |





Hazard statements
- H225Highly flammable liquid and vapour
- H300Fatal if swallowed
- H311Toxic in contact with skin
- H314Causes severe skin burns and eye damage
- H351Suspected of causing cancer
- H411Toxic to aquatic life with long-lasting effects
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P260Do not breathe dust, fume, gas, mist, vapours or spray
- P264Wash thoroughly after handling
- P273Avoid release to the environment
- P280Wear protective gloves, clothing and eye/face protection
- P284Wear respiratory protection
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 20 °C / 68 °F |
| Transport (UN / ADR) | UN 1244 6.1/PG 1 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,T+,N |
| Risk statements (R) | 11-24/25-26-34-40-51/53 |
| Safety statements (S) | 16-26-28-36/37/39-45-60 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Methylhydrazine used for?
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Methylhydrazine is primarily used as a reagent in chemical synthesis for creating organic intermediates and specialised chemicals, and has historical applications as a rocket propellant component.
What is the CAS number and formula for Methylhydrazine?
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The CAS number for Methylhydrazine is 60-34-4, and its linear formula is CH3NHNH2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Methylhydrazine with an assay of ≥98.0% (GC). We do not represent this product as USP, BP, EP, or other pharmacopoeial grades.
How should Methylhydrazine be handled safely?
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Methylhydrazine is highly flammable and toxic. Handle with extreme caution in a well-ventilated area or fume hood, wearing appropriate personal protective equipment including gloves, goggles, face shields, and a suitable respirator. Avoid ignition sources.
Is Methylhydrazine a controlled substance?
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Methylhydrazine is listed under UN 1244, Hazard Class 6.1 (Toxic substances), with a subsidiary hazard of Class 3 (Flammable liquids) and is classified as highly toxic.
How is Methylhydrazine packed, shipped, and exported?
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Methylhydrazine is carefully packed according to international shipping regulations for hazardous materials. TSS exports this chemical globally, adhering to all relevant transport and customs requirements.
How can I request a quote or sample for Methylhydrazine?
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To request a quote or sample for Methylhydrazine, please contact our sales department via the website or your dedicated account manager.
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