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Methylhydrazine

CAS 60-34-4CH3NHNH2Organic Building Blocks

Methylhydrazine (CAS 60-34-4), a volatile and flammable liquid with the molecular formula CH3NHNH2 and a molar mass of 46.07 g/mol, is a key organic building block. It is primarily recognised for its reactivity as a strong reducing agent and nucleophile. This compound finds significant application in chemical synthesis, particularly in the production of various organic intermediates and specialised chemicals.

IUPAC
MMH
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Methylhydrazine (CH3NHNH2) — chemical structure, CAS 60-34-4; Chemistry, fine chemical supplied by Tech Serve Solutions
Building BlocksChemical SynthesisHydrazinesNitrogen CompoundsOrganic Building Blocks
01 /Applications

Chemical Synthesis

Methylhydrazine serves as a versatile reagent in organic synthesis, enabling the formation of diverse heterocyclic compounds and nitrogen-containing molecules. Its nucleophilic character makes it valuable for introducing hydrazine functionalities into organic structures.

Rocket Propellant Component

Historically, methylhydrazine has been investigated and used as a component in hypergolic rocket propellants due to its high energy density and rapid ignition characteristics when combined with oxidisers.

Precursor for Organic Intermediates

It acts as a precursor in the synthesis of pharmaceuticals, agrochemicals, and dyes, where the hydrazine moiety is incorporated into more complex molecular architectures.

02 /Properties
Molecular weight46.07
Linear formulaCH3NHNH2
Assay≥98.0% (GC)
Boiling point88-90 °C(lit.)
Density0.875 g/mL at 20 °C(lit.)
Refractive indexn20/D 1.4325(lit.)n20/D 1.434
Vapour pressure37.5 mmHg (20 °C)
Vapour density1.6 (vs air)
Autoignition temp385 °F
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Toxic (GHS06)
Toxic
GHS hazard pictogram: Health hazard (GHS08)
Health hazard
GHS hazard pictogram: Environmental hazard (GHS09)
Environmental hazard
Danger

Hazard statements

  • H225Highly flammable liquid and vapour
  • H300Fatal if swallowed
  • H311Toxic in contact with skin
  • H314Causes severe skin burns and eye damage
  • H351Suspected of causing cancer
  • H411Toxic to aquatic life with long-lasting effects

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P260Do not breathe dust, fume, gas, mist, vapours or spray
  • P264Wash thoroughly after handling
  • P273Avoid release to the environment
  • P280Wear protective gloves, clothing and eye/face protection
  • P284Wear respiratory protection
Protective equipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Flash point20 °C / 68 °F
Transport (UN / ADR)UN 1244 6.1/PG 1
Water hazard class (WGK, DE)3
Hazard codes (EU)F,T+,N
Risk statements (R)11-24/25-26-34-40-51/53
Safety statements (S)16-26-28-36/37/39-45-60

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
60-34-4
MDL number
MFCD00007621
PubChem substance
24885277
Beilstein registry
635645
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Methylhydrazine used for?

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Methylhydrazine is primarily used as a reagent in chemical synthesis for creating organic intermediates and specialised chemicals, and has historical applications as a rocket propellant component.

What is the CAS number and formula for Methylhydrazine?

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The CAS number for Methylhydrazine is 60-34-4, and its linear formula is CH3NHNH2.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Methylhydrazine with an assay of ≥98.0% (GC). We do not represent this product as USP, BP, EP, or other pharmacopoeial grades.

How should Methylhydrazine be handled safely?

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Methylhydrazine is highly flammable and toxic. Handle with extreme caution in a well-ventilated area or fume hood, wearing appropriate personal protective equipment including gloves, goggles, face shields, and a suitable respirator. Avoid ignition sources.

Is Methylhydrazine a controlled substance?

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Methylhydrazine is listed under UN 1244, Hazard Class 6.1 (Toxic substances), with a subsidiary hazard of Class 3 (Flammable liquids) and is classified as highly toxic.

How is Methylhydrazine packed, shipped, and exported?

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Methylhydrazine is carefully packed according to international shipping regulations for hazardous materials. TSS exports this chemical globally, adhering to all relevant transport and customs requirements.

How can I request a quote or sample for Methylhydrazine?

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To request a quote or sample for Methylhydrazine, please contact our sales department via the website or your dedicated account manager.

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