Tri-1-naphthylphosphine
Tri-1-naphthylphosphine (CAS 3411-48-1), with the molecular formula (C10H7)3P and a molar mass of 412.46 g/mol, is a phosphine compound primarily utilised in chemical synthesis. It is widely recognised for its role as a ligand in catalysis, particularly in organometallic chemistry. Its bulky naphthyl groups can influence reaction selectivity and stability, making it a valuable reagent for advanced chemical transformations.
- IUPAC
- P(1-nap)3,Tris(1-naphthyl)phosphine
- Synonyms
- Tris(1-naphthyl)phosphineP(1-nap)3

Catalysis
Tri-1-naphthylphosphine serves as a versatile ligand in homogeneous catalysis, facilitating a range of organic transformations. Its steric and electronic properties can be tuned to influence catalyst activity and selectivity in reactions such as cross-couplings.
Organometallic Chemistry
As a phosphine ligand, it readily coordinates with transition metals, forming stable complexes. These complexes are investigated for their catalytic potential and in fundamental studies of organometallic bonding and reactivity.
Chemical Synthesis
This compound is employed in the synthesis of complex organic molecules, where its unique structural features contribute to the development of novel synthetic methodologies. It is a key building block for researchers in organic and medicinal chemistry.
| Molecular weight | 412.46 |
|---|---|
| Linear formula | (C10H7)3P |
| Assay | 97% |
| Melting point | 261-265 °C |

Hazard statements
- H302Harmful if swallowed
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xn |
| Risk statements (R) | 22 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Tri-1-naphthylphosphine used for?
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Tri-1-naphthylphosphine is primarily used as a ligand in catalysis and in organometallic chemistry, as well as a reagent in chemical synthesis.
What are the CAS number and formula for Tri-1-naphthylphosphine?
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The CAS number is 3411-48-1 and the linear formula is (C10H7)3P.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Tri-1-naphthylphosphine with an assay of 97%. This is a technical/research grade; TSS does not represent it as USP, BP, or EP grade.
How should Tri-1-naphthylphosphine be handled safely?
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Tri-1-naphthylphosphine is classified as harmful if swallowed (H302). Appropriate personal protective equipment, including a dust mask (type N95 US), eyeshields, and gloves, should be worn during handling.
How is Tri-1-naphthylphosphine packed and shipped?
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Tri-1-naphthylphosphine is carefully packed to ensure safe transit and is exported globally by TSS. Specific packaging details can be provided upon request.
How can I request a sample or quote for Tri-1-naphthylphosphine?
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To request a sample or obtain a quotation for Tri-1-naphthylphosphine, please contact the TSS sales team through our website or by phone.
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