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Potassium tert-butoxide

CAS 865-47-4(CH3)3COKAcids & Bases

Potassium tert-butoxide (CAS: 865-47-4) is a strong, non-nucleophilic base widely employed in organic synthesis. Its linear formula is (CH3)3COK, and it has a molecular weight of 112.21 g/mol. This compound is crucial for various deprotonation reactions and elimination processes. Supplied by TSS as a reagent with high purity, it serves as a valuable tool in research and industrial chemical applications, facilitating complex organic transformations.

IUPAC
Potassium tert-butylate,Potassium t-butoxide
Synonyms
Potassium tert-butylatePotassium t-butoxide
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Potassium tert-butoxide ((CH3)3COK) — chemical structure, CAS 865-47-4; Chemistry, fine chemical supplied by Tech Serve Solutions
Acids & BasesBasesChemical SynthesisOrganic BasesSynthetic Reagents
01 /Applications

Organic Synthesis Reagent

Potassium tert-butoxide is extensively used as a strong base in organic synthesis, particularly for dehydrohalogenation reactions and as a catalyst in condensation reactions like the Stobbe condensation.

Deprotonation Agent

Its sterically hindered nature makes it an effective, non-nucleophilic base for selectively removing protons from carbon acids, leading to carbanion formation in sophisticated synthetic pathways.

Polymerisation Initiator

It can serve as an initiator in certain anionic polymerisation processes, contributing to the controlled synthesis of polymers with specific molecular architectures.

02 /Properties
Molecular weight112.21
Linear formula(CH3)3COK
Assay≥97.0% (T)
Density0.82 g/mL at 25 °C
Concentration1.0 M in tert-butanol
Vapour pressure1 mmHg (220 °C)
Impurities tested≤2% K2(CO)3 and KOH
Melting point256-258 °C (dec.)(lit.)
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
Danger

Hazard statements

  • H228Flammable solid
  • H252
  • H314Causes severe skin burns and eye damage

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P235Keep cool
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentEyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Transport (UN / ADR)UN 3206 4.2/PG 2
Water hazard class (WGK, DE)1
Hazard codes (EU)F,C
Risk statements (R)11-14-35
Safety statements (S)7/9-16-26-36/37/39-43-45
Supplemental hazardsReacts violently with water.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
865-47-4
MDL number
MFCD00012162
Beilstein registry
3556712
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Potassium tert-butoxide used for?

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Potassium tert-butoxide is a strong, non-nucleophilic base primarily used in organic synthesis for dehydrohalogenation, deprotonation of carbon acids, and catalysing condensation reactions.

What is the CAS number and formula for Potassium tert-butoxide?

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The CAS number is 865-47-4, and its linear formula is (CH3)3COK.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Potassium tert-butoxide with an assay of ≥97.0% (T). We do not represent this product as USP, BP, or EP grade.

How should Potassium tert-butoxide be handled safely?

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Potassium tert-butoxide is flammable and corrosive. It reacts violently with water, necessitating handling under inert atmosphere with appropriate personal protective equipment, including eyeshields, gloves, and respiratory protection. Refer to the safety data sheet for full details.

Is Potassium tert-butoxide a controlled substance?

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No, Potassium tert-butoxide is not listed as a controlled substance.

How is Potassium tert-butoxide packed and shipped?

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Products are packed in compliance with international shipping regulations. We export globally, ensuring safe transit. Please contact us for specific packaging details.

How can I request a quote or sample?

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To request a quote or sample, please contact our sales team via the website or provide your details, and we will respond promptly.

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