Nickel peroxide
Nickel peroxide (CAS: 12035-36-8, NiO2, MW: 90.69) is a chemical compound recognised for its utility as an oxidizing agent and catalyst. It finds application in various synthetic procedures, including the solvent-free oxidation of alcohols and the chemoselective oxidation of organic compounds. Nickel peroxide is also employed in the development of novel catalytic systems, such as those for carbon monoxide oxidation and the degradation of organic dyes.
- IUPAC
- Nickel dioxide,Nickel oxide
Catalyst in Oxidation Reactions
Nickel peroxide serves as a catalyst for the oxidation of carbon monoxide and facilitates the microwave-induced catalytic degradation of crystal violet. Its unique properties enable site-specific reactivity in hybrid structures.
Reagent for Organic Synthesis
This compound is used as a reagent for solvent-free oxidation of alcohols and chemoselective oxidation of organic molecules, particularly when inductive heating is applied. It has been instrumental in improving the synthesis of methoxy cephalosporin intermediates.
Study of Reactivity Trends
Nickel peroxide is utilized in research to investigate reactivity trends in catalyzed oxidation processes involving anionic transition metal oxide clusters, specifically for carbon monoxide oxidation.
| Molecular weight | 90.69 |
|---|---|
| Empirical formula | NiO2 |
| Assay | ~30% active peroxide basis |
| Grade | oxidizing agenttechnical |
| Application | Catalyst for: • One-dimensional oxide-metal hybrid structures and site-specific enhanced reactivity for CO oxidation1• Microwave induced catalytic degradation of crystal violet2Used to study differences in reactivity trends for carbon monoxide catalyzed oxidation caused by anionic transition metal oxide clusters3Reagent: • For solvent-free oxidation of alcohols†• For chemoselective oxidation of organic compounds using inductive heating4 • To improve the synthesis of methoxy cephalosporin′s intermediate5 |
Hazard statements
- H317May cause an allergic skin reaction
- H350I
- H372Causes damage to organs through prolonged exposure
- H413May cause long-lasting harmful effects to aquatic life
Precautionary statements
- P201Obtain special instructions before use
- P280Wear protective gloves, clothing and eye/face protection
- P308IF exposed or concerned
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 1479 5.1 / PGII |
| Water hazard class (WGK, DE) | 1 |
| Hazard codes (EU) | T |
| Risk statements (R) | 49-43-48/23-53 |
| Safety statements (S) | 53-45-61 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Nickel peroxide used for?
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Nickel peroxide is primarily used as a catalyst and reagent in various oxidation reactions, including the oxidation of alcohols and organic compounds, as well as in catalytic degradation processes and research into reactivity trends.
What are the CAS number and chemical formula for Nickel peroxide?
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The CAS number for Nickel peroxide is 12035-36-8, and its chemical formula is NiO2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Nickel peroxide as a technical grade oxidizing agent with an assay of approximately 30% active peroxide. This product is not represented as USP, BP, or EP grade.
What are the safety considerations when handling Nickel peroxide?
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Nickel peroxide is a dangerous substance requiring careful handling. It may cause an allergic skin reaction (H317), is suspected of causing cancer by inhalation (H350i), can cause damage to organs through prolonged or repeated exposure (H372), and may cause long lasting harmful effects to aquatic life (H413). Full personal protective equipment, including eyeshields, face shields, and appropriate respirators and gloves, is essential. Always consult the Safety Data Sheet before use.
How is Nickel peroxide packed, shipped, and exported?
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Nickel peroxide is shipped as UN 1479, Hazard Class 5.1, Packing Group II. Tech Serve Solutions complies with all international regulations for the safe export of hazardous chemicals.
How can I request a quote or sample of Nickel peroxide?
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To request a quote or sample of Nickel peroxide, please contact our sales team via the website or by phone, providing your specific requirements and shipping details.
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