Triruthenium dodecacarbonyl
Triruthenium dodecacarbonyl (CAS: 15243-33-1, Formula: Ru3(CO)12, Molar Mass: 639.33) is a ruthenium carbonyl cluster. It serves as a valuable precursor in chemical vapour deposition (CVD) and atomic layer deposition (ALD) processes. This compound is also recognised for its utility as a H-transfer catalyst and in various synthetic organic chemistry applications, particularly involving carbonylation reactions.
- IUPAC
- Ruthenium carbonyl,tri-Ruthenium dodecacarbonyl

CVD and ALD Precursor
Triruthenium dodecacarbonyl functions as a precursor for thin film deposition techniques like Chemical Vapour Deposition (CVD) and Atomic Layer Deposition (ALD). This application is relevant in microelectronics fabrication and materials science.
Catalysis
This organometallic compound acts as a catalyst in hydrogen-transfer reactions. It has been employed in the reductive carbonylation of aromatic nitro compounds to carbamates and in the catalysis of allylic amination of olefins.
Chemical Synthesis
The compound is utilised as a reagent in chemical synthesis, particularly in reactions involving carbonylation. Its ability to form stable carbonyl clusters makes it a useful building block.
Materials Science
Triruthenium dodecacarbonyl finds application in materials science, potentially in the development of novel materials or surface modifications through deposition processes.
| Molecular weight | 639.33 |
|---|---|
| Linear formula | Ru3(CO)12 |
| Assay | 99% |
| Application | Carbonyl cluster precursor and H-transfer catalyst.1,2 Used in the reductive carbonylation of aromatic nitro compounds to carbamates.2 The phosphine-stabilized carbonyl cluster has been tethered to oxide supports.3 Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.4,5 |

Hazard statements
- H332Harmful if inhaled
| Protective equipment | dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xn |
| Risk statements (R) | 20 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Triruthenium dodecacarbonyl used for?
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Triruthenium dodecacarbonyl (CAS: 15243-33-1) is used as a precursor in CVD and ALD, and as a catalyst in various chemical transformations including H-transfer reactions and reductive carbonylation.
What are the CAS number and formula for Triruthenium dodecacarbonyl?
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The CAS number is 15243-33-1, and the chemical formula is Ru3(CO)12.
What grade and purity does Tech Serve Solutions supply for Triruthenium dodecacarbonyl?
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Tech Serve Solutions supplies Triruthenium dodecacarbonyl with an assay of 99%. We do not represent this product as USP, BP, EP, or any other pharmacopoeia grade.
What are the safety and handling considerations for Triruthenium dodecacarbonyl?
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Warning: Harmful if inhaled (H332). Appropriate personal protective equipment includes a dust mask (type N95), eyeshields, full-face particle respirator (type N100), gloves, and suitable respirator cartridges (type N100) or filters (type P1 or P3).
How is Triruthenium dodecacarbonyl packed, shipped, and exported?
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Triruthenium dodecacarbonyl is carefully packed to ensure safe transport and is available for global export by Tech Serve Solutions, a specialist supplier established in 1998.
How can I request a quote or sample for Triruthenium dodecacarbonyl?
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To request a quote or a sample of Triruthenium dodecacarbonyl, please contact the Tech Serve Solutions sales team through our website or direct contact information.
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