Benzoylferrocene
Benzoylferrocene (CAS 1272-44-2; C17H14FeO; molar mass 290.14 g/mol) is an organoiron compound, the phenyl ketone derivative of ferrocene, supplied as a crystalline solid (melting point 105-107 °C). Also known as ferrocenyl phenyl ketone, it is a versatile reactant in organometallic synthesis, used in deprotonative metalation of ferrocenes, oxidative and reduction chemistry, and the preparation of chiral ferrocenyl building blocks. Tech Serve Solutions supplies it at ≥ 98% assay for research and synthesis.
- IUPAC
- (Benzoylcyclopentadienyl)cyclopentadienyliron,Ferrecenophenone,Ferrocenyl phenyl ketone,Ferrocenyl(phenyl)methanone,NSC 54800
- Synonyms
- BenzoylferroceneFerrocenyl phenyl ketoneFerrocenyl(phenyl)methanoneFerrocenophenone(Benzoylcyclopentadienyl)cyclopentadienylironNSC 54800CAS 1272-44-2
Deprotonative metalation of ferrocenes
Benzoylferrocene serves as a reactant in the deprotonative metalation of ferrocenes, providing a route to functionalised ferrocenyl intermediates used in further organometallic synthesis.
Oxidative and reduction chemistry
The compound is employed in oxidative transformations and, as a ferrocenyl ketone, in reduction chemistry. These reactions allow the carbonyl and ferrocene units to be elaborated into more complex structures.
Chiral ferrocenyl building blocks
It is used to prepare chiral ferrocenyl alcohols via asymmetric transfer hydrogenation and planar-chiral triferrocenylmethane derivatives, supporting work in asymmetric catalysis and chiral ligand design.
Phosphaalkene polymerisation
Benzoylferrocene is a reactant in the polymerisation of C-ferrocenyl-substituted phosphaalkenes, contributing to the synthesis of iron-containing macromolecular materials.
Organometallic research reagent
More broadly, this redox-active ferrocene derivative is used as a laboratory reagent and reference material in academic and industrial organometallic chemistry research.
| Molecular weight | 290.14 |
|---|---|
| Empirical formula | C17H14FeO |
| Assay | ≥98% |
| Application | Reactant for:• Deprotonative metalation of ferrocenes1• Oxidative chemistry2• Reduction of ferrocenyl ketones3• Polymerization of C-ferrocenyl-substituted phosphaalkene4Reactant for synthesis of:• Planat chiral triferrocenylmethane derivative5• Chiral ferrocenyl alcohols via asymmetric transfer hydrogenation6 |
| Melting point | 105-107 °C(lit.) |
| Protective equipment | Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
|---|---|
| Water hazard class (WGK, DE) | 3 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Benzoylferrocene used for?
+
Benzoylferrocene is used primarily as a reactant and building block in organometallic synthesis. Documented uses include deprotonative metalation of ferrocenes, oxidative and reduction chemistry of ferrocenyl ketones, polymerisation of C-ferrocenyl-substituted phosphaalkenes, and the preparation of chiral ferrocenyl alcohols and planar-chiral triferrocenylmethane derivatives.
What is the CAS number and molecular formula of Benzoylferrocene?
+
Benzoylferrocene has the CAS number 1272-44-2 and the empirical formula C17H14FeO (Hill notation), with a molecular weight of 290.14 g/mol. Its EC number is 215-054-2 and its MDL number is MFCD00001431.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies Benzoylferrocene at an assay of ≥ 98%, as a research and synthesis-grade reagent (reported melting point 105-107 °C). We do not represent it as USP, BP or EP pharmacopoeia grade. A certificate of analysis can be provided with each batch on request.
How should Benzoylferrocene be handled and stored?
+
Handle Benzoylferrocene using standard laboratory precautions for fine chemicals: wear eye protection and gloves, and use a suitable respirator (N95/P1) where dust may be generated. It is classified under German Water Hazard Class WGK 3 (severely hazardous to water), so it must be kept out of drains and watercourses and disposed of as chemical waste. Always consult the current Safety Data Sheet before use.
How is Benzoylferrocene packed, shipped and exported?
+
Benzoylferrocene is packed as a solid in tightly sealed, labelled containers sized from research quantities to bulk, with packaging selected to protect the material in transit. Each consignment ships with the appropriate documentation, including a Safety Data Sheet, and Tech Serve Solutions exports worldwide in line with applicable transport and customs requirements.
How do I request a sample or quote for Benzoylferrocene?
+
To request a sample, current pricing or a formal quotation, contact Tech Serve Solutions with your required quantity, purity and destination. We will confirm availability, lead time and documentation, and can supply a certificate of analysis for your specification.
▶ Related products
Benzeneruthenium(II) chloride dimer
Ru2(C6H6)2Cl4
Catalysis & Inorganic
Benzyldiphenylphosphine
C6H5CH2P(C6H5)2
Catalysis & Inorganic
Beryllium
Be
Catalysis & Inorganic
Beryllium oxide
BeO
Catalysis & Inorganic![Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer — chemical structure, CAS 12257-42-0; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F12257-42-0.png&w=3840&q=75)
Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer
Catalysis & Inorganic
![Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluorobo — chemical structure, CAS 1228149-03-8; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1228149-03-8.png&w=3840&q=75)
Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluorobo
1-d:1′
Catalysis & Inorganic![Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride (C16H20ClN3Ni) — chemical structure, CAS 1033772-47-2; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1033772-47-2.png&w=3840&q=75)
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
C16H20ClN3Ni
Catalysis & Inorganic![Bis[(dicyclohexyl)(4-dimethylaminophenyl)phosphine] palladium(II) chloride — chemical structure, CAS 945375-77-9; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F945375-77-9.png&w=3840&q=75)
Bis[(dicyclohexyl)(4-dimethylaminophenyl)phosphine] palladium(II) chloride
Catalysis & Inorganic
▶ Explore more
3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis
3-Methyl-1,5-pentanediol
Chemical Synthesis
3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis