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Zirconium(IV) chloride tetrahydrofuran complex (1:2)

CAS 21959-01-3ZrCl4 · 2OC4H8Catalysis & Inorganic

Zirconium(IV) chloride tetrahydrofuran complex (1:2), CAS 21959-01-3, features the linear formula ZrCl<sub>4</sub> · 2OC<sub>4</sub>H<sub>8</sub> and a molecular weight of 377.25 g/mol. This white to off-white powder is a stable, soluble complex of zirconium tetrachloride with tetrahydrofuran. It is commonly employed as a precursor in the synthesis of organozirconium compounds and finds application as a catalyst in various organic transformations, particularly in polymerisation and coupling reactions.

IUPAC
Tetrachlorobis(tetrahydrofuran)zirconium,Zirconium tetrachloride tetrahydrofuran complex
Synonyms
Tetrachlorobis(tetrahydrofuran)zirconium,Zirconium tetrachloride tetrahydrofuran complex
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Zirconium(IV) chloride tetrahydrofuran complex (1:2) (ZrCl4 · 2OC4H8) — chemical structure, CAS 21959-01-3; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisEssential ChemicalsMaterials ScienceMetal and Ceramic ScienceResearch EssentialsSaltsZirconiumZirconium Salts More...
01 /Applications

Catalysis

This zirconium complex acts as an effective catalyst in organic synthesis, facilitating reactions such as polymerisation and carbon-carbon bond formation. Its Lewis acidity makes it valuable for promoting various transformations in academic and industrial research.

Chemical Synthesis

It serves as a convenient and stable source of zirconium(IV) for the preparation of organometallic compounds and coordination complexes. The tetrahydrofuran ligands enhance its solubility and handling properties compared to anhydrous zirconium tetrachloride.

Materials Science

The compound can be utilised as a precursor in the development of advanced materials, including ceramics and thin films, where precise control over zirconium incorporation is required.

02 /Properties
Molecular weight377.25
Linear formulaZrCl4 · 2OC4H8
Assay99%
Formpowder
Vapour pressure152 mmHg (25 °C)(lit.)
Storage temperature2-8°C
Melting point175-177 °C(lit.)
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Danger

Hazard statements

  • H228Flammable solid
  • H302Harmful if swallowed
  • H312Harmful in contact with skin
  • H314Causes severe skin burns and eye damage
  • H332Harmful if inhaled

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentEyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Transport (UN / ADR)UN 2925 4.1/PG 2
Water hazard class (WGK, DE)3
Hazard codes (EU)C
Risk statements (R)20/21/22-34
Safety statements (S)22-26-36/37/39-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
21959-01-3
MDL number
MFCD00145367
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Zirconium(IV) chloride tetrahydrofuran complex (1:2) used for?

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Zirconium(IV) chloride tetrahydrofuran complex (1:2) is primarily used as a catalyst in organic synthesis, particularly for polymerisation and coupling reactions, and as a precursor in the synthesis of organozirconium compounds and advanced materials.

What is the CAS number and formula for Zirconium(IV) chloride tetrahydrofuran complex (1:2)?

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The CAS number is 21959-01-3 and the linear formula is ZrCl <sub>4</sub> &middot; 2OC <sub>4</sub>H <sub>8</sub>.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Zirconium(IV) chloride tetrahydrofuran complex (1:2) with an assay of 99%. We do not represent this product as USP, BP, EP, or any other pharmacopoeia grade.

How should Zirconium(IV) chloride tetrahydrofuran complex (1:2) be handled?

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This compound is a Danger hazard material, classified as H228 (Flammable solid), H302 (Harmful if swallowed), H312 (Harmful in contact with skin), and H314 (Causes severe skin burns and eye damage). Handle with appropriate personal protective equipment, including eyeshields, faceshields, chemical-resistant gloves, and respiratory protection (type N100/P3). Ensure adequate ventilation and avoid contact with skin, eyes, and clothing.

Is Zirconium(IV) chloride tetrahydrofuran complex (1:2) a controlled substance?

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No, Zirconium(IV) chloride tetrahydrofuran complex (1:2) is not listed as a controlled substance.

How is Zirconium(IV) chloride tetrahydrofuran complex (1:2) packed and shipped?

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This product is packed and shipped according to UN 2925 regulations for hazardous materials, with hazard class 4.1 (Flammable solid). TSS ensures all shipments comply with international export regulations.

How can I request a quote or sample?

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To request a quote or sample of Zirconium(IV) chloride tetrahydrofuran complex (1:2), please contact our sales department through the website or by calling us directly.

Need Zirconium(IV) chloride tetrahydrofuran complex (1:2) in a specific grade or volume?