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Zirconium(IV) chloride

CAS 10026-11-6ZrCl4Catalysis & Inorganic

Zirconium(IV) chloride (CAS: 10026-11-6) is an anhydrous inorganic compound with the chemical formula ZrCl4. This white crystalline powder has a molecular weight of 233.04 g/mol. It is known for its reactivity, particularly with water, and finds significant utility as a precursor in materials science, a catalyst in chemical synthesis, and in the production of other zirconium compounds. Its high purity makes it suitable for demanding research and industrial applications.

IUPAC
Tetrachlorozirconium,Zirconium tetrachloride
Synonyms
TetrachlorozirconiumZirconium tetrachloride
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Zirconium(IV) chloride (ZrCl4) — chemical structure, CAS 10026-11-6; Chemistry, fine chemical supplied by Tech Serve Solutions
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01 /Applications

Catalysis

Zirconium(IV) chloride serves as a Lewis acid catalyst in various organic transformations. It is employed in Friedel-Crafts reactions, polymerization processes, and as a catalyst in the synthesis of complex organic molecules and polymers.

Materials Science Precursor

This compound is a key precursor for the deposition of zirconium dioxide (ZrO2) and other zirconium-containing thin films via chemical vapor deposition (CVD) or atomic layer deposition (ALD). These films are essential in microelectronics, optics, and protective coatings.

Synthesis of Zirconium Compounds

Zirconium(IV) chloride is a versatile intermediate for synthesising a wide range of other zirconium-based chemicals, including organozirconium complexes and various inorganic zirconium salts. These derivatives have diverse applications in catalysis and materials science.

Crystal Growth

The compound's sublimation properties at 331 °C make it suitable for crystal growth techniques, enabling the formation of high-purity zirconium-based crystals for research and specialized applications.

02 /Properties
Molecular weight233.04
Linear formulaZrCl4
Assay99.99% trace metals basis
Gradeanhydrous
Formpowder
Density2.8 g/mL at 25 °C(lit.)
Vapour pressure1 mmHg (190 °C)
Impurities tested<50 ppm hafnium
03 /Safety & handling
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
Danger

Hazard statements

  • H290May be corrosive to metals
  • H314Causes severe skin burns and eye damage

Precautionary statements

  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentEyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Transport (UN / ADR)UN 2503 8 / PGIII
Water hazard class (WGK, DE)3
Hazard codes (EU)C
Risk statements (R)14-35
Safety statements (S)26-36/37/39-45
Supplemental hazardsCorrosive to the respiratory tract., Reacts violently with water.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
10026-11-6
MDL number
MFCD00011306
PubChem substance
24883414
05 /Additional specifications
Transition Tempsublimation point 331 °C
06 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

07 /Frequently asked questions

What is Zirconium(IV) chloride used for?

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Zirconium(IV) chloride is primarily used as a catalyst in chemical synthesis, a precursor in materials science for depositing zirconium-containing thin films, and as an intermediate for producing other zirconium compounds.

What is the CAS number and chemical formula for Zirconium(IV) chloride?

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The CAS number for Zirconium(IV) chloride is 10026-11-6, and its chemical formula is ZrCl4.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Zirconium(IV) chloride in an anhydrous grade with a purity of 99.99% (trace metals basis), containing less than 50 ppm hafnium.

How should Zirconium(IV) chloride be handled safely?

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Zirconium(IV) chloride is corrosive and reacts violently with water. Handle with extreme care in a well-ventilated area, wearing appropriate personal protective equipment including eyeshields, gloves, and a respirator. Avoid contact with moisture.

Is Zirconium(IV) chloride a controlled substance?

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The provided data does not indicate that Zirconium(IV) chloride is a controlled substance.

How is Zirconium(IV) chloride packed, shipped, and exported?

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Zirconium(IV) chloride is shipped as UN 2503, Hazard Class 8, Packing Group III. Specific packaging details will be confirmed upon order, adhering to international shipping regulations.

How can I request a quote or sample for Zirconium(IV) chloride?

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To request a quote or sample, please contact our sales team via the website or provide your details through the product enquiry form. Our team will respond promptly.

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