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Zinc di[bis(trifluoromethylsulfonyl)imide]

CAS 168106-25-0C4F12N2O8S4ZnCatalysis & Inorganic

Zinc di[bis(trifluoromethylsulfonyl)imide], CAS 168106-25-0, is a specialised zinc salt with the molecular formula C4F12N2O8S4Zn. This compound functions as an effective catalyst in various organic transformations. Its applications include facilitating enantioselective Friedel-Crafts alkylations, stereoselective Diels-Alder reactions, and tandem cyclopropane ring-opening/Conia-ene cyclizations. Available from Tech Serve Solutions, it is a valuable reagent for synthetic chemists seeking efficient catalytic systems.

IUPAC
Zn(NTf2)2
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Zinc di[bis(trifluoromethylsulfonyl)imide] (C4F12N2O8S4Zn) — chemical structure, CAS 168106-25-0; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisZinc
01 /Applications

Enantioselective Friedel-Crafts Alkylation

Catalyses the enantioselective Friedel-Crafts alkylation of pyrroles with β-trifluoromethyl acrylates, offering precise control over stereochemistry in complex molecule synthesis.

Stereoselective Diels-Alder Reaction

Acts as a catalyst for stereoselective Diels-Alder reactions, a fundamental transformation in organic chemistry for constructing cyclic systems with defined stereochemistry.

Tandem Cyclopropane Ring-Opening / Conia-ene Cyclization

Facilitates tandem cyclopropane ring-opening and Conia-ene cyclization processes, enabling efficient synthesis of complex polycyclic structures in a single step.

Aromatic Nitration

Employed as a catalyst in the aromatic nitration of various substrates, contributing to the functionalisation of aromatic rings with nitro groups.

02 /Properties
Molecular weight625.68
Empirical formulaC4F12N2O8S4Zn
Assay95%
ApplicationCatalyst for:• Enantioselective Friedel-Crafts alkylation of pyrroles with β-CF3 acrylates1• Stereoselective Diels-Alder reaction2• Tandem cyclopropane ring-opening / Conia-ene cyclization3• Aromatic nitration4
Melting point143-147 °C
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Warning

Hazard statements

  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H335May cause respiratory irritation

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P305IF IN EYES
Flash point>110 °C / >230 °F
Water hazard class (WGK, DE)3
Hazard codes (EU)Xi
Risk statements (R)36/37/38
Safety statements (S)26-36/37/39

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
168106-25-0
MDL number
MFCD16621474
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Zinc di[bis(trifluoromethylsulfonyl)imide] used for?

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Zinc di[bis(trifluoromethylsulfonyl)imide] (CAS 168106-25-0) is primarily used as a catalyst for several important organic reactions, including enantioselective Friedel-Crafts alkylations, stereoselective Diels-Alder reactions, tandem cyclopropane ring-opening/Conia-ene cyclizations, and aromatic nitration.

What is the CAS number and formula for Zinc di[bis(trifluoromethylsulfonyl)imide]?

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The CAS number is 168106-25-0, and the molecular formula is C4F12N2O8S4Zn.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Zinc di[bis(trifluoromethylsulfonyl)imide] with an assay of 95%. This product is not graded as USP, BP, EP, or any other pharmacopoeia standard.

What are the main hazards associated with Zinc di[bis(trifluoromethylsulfonyl)imide]?

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This compound is classified with a GHS07 symbol and carries a Warning signal word. It causes skin irritation (H315), serious eye irritation (H319), and may cause respiratory irritation (H335). Handle with appropriate personal protective equipment in a well-ventilated area.

How is this chemical packed, shipped, and exported?

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As a specialist global supplier, Tech Serve Solutions ensures secure packing and handles all necessary export documentation for Zinc di[bis(trifluoromethylsulfonyl)imide] to meet international shipping regulations.

How can I request a sample or a quote for Zinc di[bis(trifluoromethylsulfonyl)imide]?

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To request a sample or obtain a quote, please contact our sales team through the website or by calling our dedicated customer service line.

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