Zinc di[bis(trifluoromethylsulfonyl)imide]
Zinc di[bis(trifluoromethylsulfonyl)imide], CAS 168106-25-0, is a specialised zinc salt with the molecular formula C4F12N2O8S4Zn. This compound functions as an effective catalyst in various organic transformations. Its applications include facilitating enantioselective Friedel-Crafts alkylations, stereoselective Diels-Alder reactions, and tandem cyclopropane ring-opening/Conia-ene cyclizations. Available from Tech Serve Solutions, it is a valuable reagent for synthetic chemists seeking efficient catalytic systems.
- IUPAC
- Zn(NTf2)2
![Zinc di[bis(trifluoromethylsulfonyl)imide] (C4F12N2O8S4Zn) — chemical structure, CAS 168106-25-0; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F168106-25-0.png&w=3840&q=75)
Enantioselective Friedel-Crafts Alkylation
Catalyses the enantioselective Friedel-Crafts alkylation of pyrroles with β-trifluoromethyl acrylates, offering precise control over stereochemistry in complex molecule synthesis.
Stereoselective Diels-Alder Reaction
Acts as a catalyst for stereoselective Diels-Alder reactions, a fundamental transformation in organic chemistry for constructing cyclic systems with defined stereochemistry.
Tandem Cyclopropane Ring-Opening / Conia-ene Cyclization
Facilitates tandem cyclopropane ring-opening and Conia-ene cyclization processes, enabling efficient synthesis of complex polycyclic structures in a single step.
Aromatic Nitration
Employed as a catalyst in the aromatic nitration of various substrates, contributing to the functionalisation of aromatic rings with nitro groups.
| Molecular weight | 625.68 |
|---|---|
| Empirical formula | C4F12N2O8S4Zn |
| Assay | 95% |
| Application | Catalyst for:• Enantioselective Friedel-Crafts alkylation of pyrroles with β-CF3 acrylates1• Stereoselective Diels-Alder reaction2• Tandem cyclopropane ring-opening / Conia-ene cyclization3• Aromatic nitration4 |
| Melting point | 143-147 °C |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Flash point | >110 °C / >230 °F |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26-36/37/39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Zinc di[bis(trifluoromethylsulfonyl)imide] used for?
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Zinc di[bis(trifluoromethylsulfonyl)imide] (CAS 168106-25-0) is primarily used as a catalyst for several important organic reactions, including enantioselective Friedel-Crafts alkylations, stereoselective Diels-Alder reactions, tandem cyclopropane ring-opening/Conia-ene cyclizations, and aromatic nitration.
What is the CAS number and formula for Zinc di[bis(trifluoromethylsulfonyl)imide]?
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The CAS number is 168106-25-0, and the molecular formula is C4F12N2O8S4Zn.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Zinc di[bis(trifluoromethylsulfonyl)imide] with an assay of 95%. This product is not graded as USP, BP, EP, or any other pharmacopoeia standard.
What are the main hazards associated with Zinc di[bis(trifluoromethylsulfonyl)imide]?
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This compound is classified with a GHS07 symbol and carries a Warning signal word. It causes skin irritation (H315), serious eye irritation (H319), and may cause respiratory irritation (H335). Handle with appropriate personal protective equipment in a well-ventilated area.
How is this chemical packed, shipped, and exported?
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As a specialist global supplier, Tech Serve Solutions ensures secure packing and handles all necessary export documentation for Zinc di[bis(trifluoromethylsulfonyl)imide] to meet international shipping regulations.
How can I request a sample or a quote for Zinc di[bis(trifluoromethylsulfonyl)imide]?
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To request a sample or obtain a quote, please contact our sales team through the website or by calling our dedicated customer service line.
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