Triphenylantimony(V) dichloride
Triphenylantimony(V) dichloride (CAS 594-31-0), with the linear formula (C6H5)3SbCl2, is an organometallic compound with a molecular weight of 423.98 g/mol. It functions as a valuable reagent and catalyst in organic synthesis. Key applications include its use in regioselective cycloaddition reactions, the synthesis of organoantimony(V) compounds, and in Suzuki-type cross couplings, highlighting its utility in advanced chemical research and development.
- IUPAC
- Dichlorotriphenylantimony(V),NSC 179782,NSC 432,Triphenylstibine dichloride
- Synonyms
- Dichlorotriphenylantimony(V)Triphenylstibine dichloride

Catalyst in Cycloaddition Reactions
This compound acts as a catalyst for the regioselective cycloaddition of aziridines with heterocumulenes. It also facilitates the reaction of epoxides with carbon dioxide, demonstrating its versatility in forming cyclic structures.
Precursor for Organoantimony Synthesis
Triphenylantimony(V) dichloride serves as a reactant for synthesising various organoantimony(V) compounds. This includes the preparation of compounds with arylcarbonyloxy moieties and the formation of symmetrical macrocyclic organoantimony(V) complexes.
Reagent in Cross-Coupling Reactions
It is employed as a reactant in oxidation reactions and plays a role in Suzuki-type cross couplings, enabling the formation of carbon-carbon bonds in complex molecules.
| Molecular weight | 423.98 |
|---|---|
| Linear formula | (C6H5)3SbCl2 |
| Assay | 99% |
| Application | Catalyst for:• Regioselective cycloaddition of aziridines with heterocumulenes1• Reaction of epoxides with carbon dioxide2Reactant for synthesis of:• Tetraphenylantimony compounds with arylcarbonyloxy moieties3• Symmetrical 24-membered macrocyclic organoantimony(V) complexes4Reactant for oxidation5 and Suzuki-type cross couplings6 |
| Melting point | 143-145 °C(lit.) |


Hazard statements
- H302Harmful if swallowed
- H332Harmful if inhaled
- H411Toxic to aquatic life with long-lasting effects
Precautionary statements
- P273Avoid release to the environment
| Protective equipment | dust mask type N95 (US), Eyeshields, Faceshields, Gloves |
|---|---|
| Transport (UN / ADR) | UN 2923 8/PG 2 |
| Water hazard class (WGK, DE) | 2 |
| Hazard codes (EU) | Xn,N |
| Risk statements (R) | 20/22-51/53 |
| Safety statements (S) | 61 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Triphenylantimony(V) dichloride used for?
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Triphenylantimony(V) dichloride is used as a catalyst for the regioselective cycloaddition of aziridines with heterocumulenes and the reaction of epoxides with carbon dioxide. It also serves as a reactant for synthesising various organoantimony(V) compounds and in oxidation and Suzuki-type cross couplings.
What is the CAS number and formula for Triphenylantimony(V) dichloride?
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The CAS number is 594-31-0 and the linear formula is (C6H5)3SbCl2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Triphenylantimony(V) dichloride with an assay of 99%. TSS does not represent this product as USP, BP, EP, or any other pharmacopoeial grade.
How should Triphenylantimony(V) dichloride be handled safely?
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Triphenylantimony(V) dichloride is harmful if swallowed and inhaled (H302, H332) and is toxic to aquatic life with long lasting effects (H411). Appropriate personal protective equipment includes a dust mask type N95 (US), eyeshields, faceshields, and gloves. Avoid release to the environment (P273).
How is Triphenylantimony(V) dichloride packed and exported?
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This product is classified under UN 2923, 8/PG 2. Tech Serve Solutions, a specialist global supplier and exporter, ensures appropriate packaging and adherence to regulations for international shipment.
How can I request a quote or sample for Triphenylantimony(V) dichloride?
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To request a quote or sample, please contact the Tech Serve Solutions sales team through our official website or designated contact channels, providing the product name and CAS number.
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