(S)-(+)-2-Methylpiperidine
(S)-(+)-2-Methylpiperidine (CAS: 3197-42-0, C6H13N) is a chiral heterocyclic amine with a molecular weight of 99.17 g/mol. It serves as a valuable building block in asymmetric synthesis and general chemical applications. Its specific stereochemistry makes it useful for creating enantiomerically pure compounds. This reagent is essential for researchers and manufacturers involved in complex organic synthesis.

Chiral Building Block
(S)-(+)-2-Methylpiperidine is employed as a chiral auxiliary or precursor in the synthesis of enantiomerically pure molecules. Its defined stereocenter allows for the stereoselective construction of complex pharmaceutical intermediates and fine chemicals.
Asymmetric Synthesis
This compound is integral to asymmetric synthesis, enabling the creation of molecules with specific spatial arrangements. It is used to introduce chirality or to control the stereochemical outcome of reactions in organic chemistry research and development.
Heterocyclic Chemistry
As a substituted piperidine, (S)-(+)-2-Methylpiperidine is a key intermediate in the synthesis of various heterocyclic compounds. These structures are prevalent in many biologically active molecules and advanced materials.
| Molecular weight | 99.17 |
|---|---|
| Empirical formula | C6H13N |
| Assay | 97% |
| Boiling point | 117-121 °C(lit.) |
| Density | 0.823 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.446(lit.) |
| Optical activity | [α]20/D +35°, c = 3.5 in hexane |


Hazard statements
- H225Highly flammable liquid and vapour
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 15 °C / 59 °F |
| Transport (UN / ADR) | UN 1993BF 3 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,Xi |
| Risk statements (R) | 11-36/37/38 |
| Safety statements (S) | 16-26-36 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is (S)-(+)-2-Methylpiperidine used for?
+
(S)-(+)-2-Methylpiperidine is primarily used as a chiral building block in asymmetric synthesis and in the preparation of complex heterocyclic compounds for research and development.
What is the CAS number and formula for (S)-(+)-2-Methylpiperidine?
+
The CAS number is 3197-42-0, and the empirical formula is C6H13N.
What grade and purity does Tech Serve Solutions supply for (S)-(+)-2-Methylpiperidine?
+
Tech Serve Solutions supplies (S)-(+)-2-Methylpiperidine with an assay of 97%. We do not represent this product as USP, BP, or EP grade; it is suitable for research and chemical synthesis applications.
How should (S)-(+)-2-Methylpiperidine be handled safely?
+
(S)-(+)-2-Methylpiperidine is a flammable liquid and vapour (H225) and can cause skin irritation (H315), serious eye irritation (H319), and respiratory irritation (H335). Handle with appropriate personal protective equipment, including eyeshields, gloves, and respiratory protection, in a well-ventilated area, away from ignition sources.
How is (S)-(+)-2-Methylpiperidine packed and shipped?
+
This chemical is shipped according to UN 1993 standards as a flammable liquid (BF 3 / PG II). Specific packaging details are available upon request, and TSS is experienced in global export.
How can I request a sample or quote for (S)-(+)-2-Methylpiperidine?
+
Please contact our sales team via the website or by phone to request a sample or a formal quotation for (S)-(+)-2-Methylpiperidine.
▶ Related products

1-(2-Fluorobenzyl)piperazine
C11H15FN2
Chemical Synthesis
1-(2-Fluorophenyl)biguanide hydrochloride
Chemical Synthesis

1-(2-Fluorophenyl)cyclopropanecarboxylic acid
C10H9FO2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine
C10H13FN2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine monohydrochloride
C10H13FN2 · HCl
Chemical Synthesis
1-(2-Furoyl)-1H-benzotriazole
C11H7N3O2
Chemical Synthesis
1-(2-Furoyl)piperazine
C9H12N2O2
Chemical Synthesis
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
Chemical Synthesis
▶ Explore more

3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis

3-Methyl-1,5-pentanediol
Chemical Synthesis

3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis