Praseodymium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate]
Praseodymium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate] (CAS: 38053-99-5) is a chiral lanthanide complex with the formula C36H42F9O6Pr and a molecular weight of 882.61 g/mol. This compound is primarily utilised in asymmetric synthesis and as a chiral shift reagent in Nuclear Magnetic Resonance (NMR) spectroscopy. Its specific stereochemistry and properties make it valuable for applications requiring precise chiral induction and analysis in advanced chemical research.
- IUPAC
- Pr(facam)3,Pr(tfc)3,Tris(3-trifluoroacetyl-d-camphorato)praseodym(III),Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]praseodymium(III)
- Synonyms
- Pr(facam)3, Pr(tfc)3, Tris(3-trifluoroacetyl-d-camphorato)praseodym(III), Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]praseodymium(III)
![Praseodymium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate] (C36H42F9O6Pr) — chemical structure, CAS 38053-99-5; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F38053-99-5.png&w=3840&q=75)
Asymmetric Synthesis
This chiral lanthanide complex serves as a catalyst or reagent in asymmetric synthesis, facilitating the stereoselective formation of chiral molecules. It is instrumental in producing enantiomerically enriched compounds essential for pharmaceutical and fine chemical industries.
Chiral Resolution Reagents
It can be employed as a chiral resolving agent to separate enantiomers of racemic mixtures. The complex interacts diastereoselectively with enantiomers, enabling their separation via crystallisation or chromatography.
NMR Chiral Shift Reagent
Praseodymium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate] is widely used as an NMR chiral shift reagent. It induces magnetic anisotropy, leading to distinct chemical shifts for enantiomers or diastereomers, thereby aiding in the determination of enantiomeric excess and structural elucidation.
Analytical Chemistry
Its paramagnetic nature and chiral properties make it a useful tool in analytical chemistry for characterising complex organic molecules. It assists in obtaining clearer NMR spectra and resolving overlapping signals for stereoisomers.
| Molecular weight | 882.61 |
|---|---|
| Empirical formula | C36H42F9O6Pr |
| Assay | 98% |
| Optical activity | [α]25/D +175°, c = 1.3 in chloroform |
| Melting point | 208-210 °C(lit.) |
| Protective equipment | Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter |
|---|---|
| Water hazard class (WGK, DE) | 3 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Praseodymium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate] used for?
+
This compound is primarily used in asymmetric synthesis, as a chiral resolution reagent, and as an NMR chiral shift reagent for determining enantiomeric excess and elucidating molecular structures in advanced chemical research.
What are the CAS number and formula for this compound?
+
The CAS number is 38053-99-5 and the empirical formula is C36H42F9O6Pr.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies this compound with an assay of 98%. It is supplied as a research or technical grade material, and TSS does not represent it as USP, BP, EP, or any other pharmacopoeia grade.
What are the safety and handling recommendations?
+
Handle this compound with appropriate personal protective equipment, including eyeshields, gloves, and a type N95 (US) or type P1 (EN143) respirator filter. Refer to the safety data sheet for detailed hazard information. WGK Germany is 3.
How is this chemical packed, shipped, and exported?
+
Tech Serve Solutions safely packs and ships this chemical globally, adhering to all relevant international regulations for hazardous materials export. Specific packaging details are available upon request.
How can I request a sample or quote?
+
To request a sample or a detailed quote, please contact our sales department through the website or by phone, providing the product name and CAS number (38053-99-5).
▶ Related products
1-(2-Fluorobenzyl)piperazine
C11H15FN2
Chemical Synthesis
1-(2-Fluorophenyl)biguanide hydrochloride
Chemical Synthesis
1-(2-Fluorophenyl)cyclopropanecarboxylic acid
C10H9FO2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine
C10H13FN2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine monohydrochloride
C10H13FN2 · HCl
Chemical Synthesis
1-(2-Furoyl)-1H-benzotriazole
C11H7N3O2
Chemical Synthesis
1-(2-Furoyl)piperazine
C9H12N2O2
Chemical Synthesis
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
Chemical Synthesis
▶ Explore more
3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis
3-Methyl-1,5-pentanediol
Chemical Synthesis
3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis