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Pentacarbonylchlororhenium(I)

CAS 14099-01-5Re(CO)5ClCatalysis & Inorganic

Pentacarbonylchlororhenium(I), CAS 14099-01-5, with the formula Re(CO)5Cl and a molecular weight of 361.71 g/mol, is a rhenium compound primarily utilised in catalysis and inorganic chemistry. It serves as a precursor for synthesising various organometallic complexes and finding application in the study of charge-transfer processes and π-electron deficient complexes. This chemical is supplied by TSS for research and development purposes.

IUPAC
Rhenium(I) pentacarbonyl chloride
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Pentacarbonylchlororhenium(I) (Re(CO)5Cl) — chemical structure, CAS 14099-01-5; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisRhenium
01 /Applications

Preparation of Tricarbonylrhenium Complexes

Pentacarbonylchlororhenium(I) is employed in the preparation of π-electron deficient complexes involving tricarbonylrhenium and diimine ligands, advancing research in coordination chemistry.

Synthesis of Ferrocenophane Compounds

This compound is utilised in the preparation of [3]-ferrocenophane complexes, contributing to the synthesis of novel organometallic structures.

Study of Charge-Transfer Processes

It is used in the preparation of mixed-valence compounds of rhenium and iron, which are integral to the investigation of charge-transfer phenomena.

02 /Properties
Molecular weight361.71
Linear formulaRe(CO)5Cl
Assay98%
ApplicationUsed to study π-electron deficient complexes between tricarbonylhalorhenium and diimine ligands1 and also to prepare [3]-ferrocenophane complexes.2 Employed in preparation of a series of mixed-valence compounds of rhenium and iron these compounds find application in the study of charge-transfer processes.3
03 /Safety & handling
GHS hazard pictogram: Toxic (GHS06)
Toxic
Danger

Hazard statements

  • H301Toxic if swallowed
  • H311Toxic in contact with skin
  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H331Toxic if inhaled
  • H335May cause respiratory irritation

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P280Wear protective gloves, clothing and eye/face protection
  • P301IF SWALLOWED
  • P305IF IN EYES
  • P311Call a POISON CENTER or doctor
Protective equipmentEyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges
Transport (UN / ADR)UN 3288 6.1 / PGIII
Water hazard class (WGK, DE)3
Hazard codes (EU)T
Risk statements (R)23/24/25-36/37/38
Safety statements (S)26-28-36/37/39-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
14099-01-5
MDL number
MFCD00013296
PubChem substance
24859674
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Pentacarbonylchlororhenium(I) used for?

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Pentacarbonylchlororhenium(I) is used to study π-electron deficient complexes, prepare [3]-ferrocenophane complexes, and synthesise mixed-valence compounds for studying charge-transfer processes.

What is the CAS number and chemical formula for Pentacarbonylchlororhenium(I)?

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The CAS number is 14099-01-5 and the chemical formula is Re(CO)5Cl.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Pentacarbonylchlororhenium(I) with an assay of 98%. TSS does not represent this product as USP, BP, EP or other pharmacopoeia grades.

How should Pentacarbonylchlororhenium(I) be handled?

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Pentacarbonylchlororhenium(I) is dangerous. It is toxic if swallowed, in contact with skin, and if inhaled, and causes skin and serious eye irritation. Handle with appropriate personal protective equipment including eyeshields, faceshields, gloves, and a type P2 respirator.

Is Pentacarbonylchlororhenium(I) a controlled substance?

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The provided data does not indicate that Pentacarbonylchlororhenium(I) is a controlled substance.

How is Pentacarbonylchlororhenium(I) packed, shipped, and exported?

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Pentacarbonylchlororhenium(I) is shipped according to UN 3288 6.1 / PGIII regulations. As a global supplier, TSS has extensive experience in exporting chemicals worldwide.

How can I request a sample or quote for Pentacarbonylchlororhenium(I)?

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To request a sample or quote, please contact the TSS sales team via our website or by calling us directly.

Need Pentacarbonylchlororhenium(I) in a specific grade or volume?