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(Methylcyclopentadienyl)manganese(I) tricarbonyl

CAS 12108-13-3C5H4CH3Mn(CO)3Catalysis & Inorganic

(Methylcyclopentadienyl)manganese(I) tricarbonyl (CAS: 12108-13-3; Formula: C5H4CH3Mn(CO)3) is an organometallic compound with a molecular weight of 218.09 g/mol. It serves as a crucial reactant in various organic synthesis pathways, including aldol addition reactions, and is utilized in materials science for doping semiconductor nanocrystals and preparing thin films. Its applications span catalysis and inorganic chemistry.

IUPAC
(Methylcyclopentadienyl)tricarbonylmanganese,Ethyl MMT,MCMT,MMT,NSC 22316,Tricarbonyl(2-methylcyclopentadienyl)manganese
Synonyms
Tricarbonyl(2-methylcyclopentadienyl)manganeseEthyl MMTMCMTMMTNSC 22316
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(Methylcyclopentadienyl)manganese(I) tricarbonyl (C5H4CH3Mn(CO)3) — chemical structure, CAS 12108-13-3; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisManganese
01 /Applications

Doping of Semiconductor Nanocrystals

This compound is employed for the doping of Zinc Selenide (ZnSe) nanocrystals, contributing to their electronic and optical properties.

Aldol Addition Reactions

It functions as a reactant in aldol addition reactions, a fundamental carbon-carbon bond-forming process in organic synthesis.

Synthesis of Mixed Carbene Complexes

Used in the preparation of homo- and heteronuclear mixed biscarbene complexes featuring conjugated bithiophene units.

Preparation of MnAs Thin Films

Applied in the Metalorganic Vapour Phase Epitaxy (MOVPE) process for growing Manganese Arsenide (MnAs) thin films on Gallium Arsenide (GaAs) substrates.

Molecular Fragmentation Studies

Investigated for its role in molecular fragmentation using shaped femtosecond laser pulses, contributing to fundamental chemical research.

02 /Properties
Molecular weight218.09
Linear formulaC5H4CH3Mn(CO)3
Boiling point232-233 °C(lit.)
Density1.38 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.584(lit.)
Vapour pressure0.05 mmHg (20 °C)
Vapour density>1 (vs air)
Melting point−1 °C(lit.)
Application• Used for doping of ZnSe nanocrystals1Reactant for:• Aldol addition reactions2• Preparation of homo- and heteronuclear mixed biscarbene complexes with conjugated bithiophene units3• Molecular fragmentation using shaped femtosecond laser pulses4• Preparation of MnAs thin films grown on GaAs(001) by metalorganic vapour phase epitaxy (MOVPE)5
03 /Safety & handling
GHS hazard pictogram: Toxic (GHS06)
Toxic
GHS hazard pictogram: Health hazard (GHS08)
Health hazard
Danger

Hazard statements

  • H300Fatal if swallowed
  • H311Toxic in contact with skin
  • H351Suspected of causing cancer

Precautionary statements

  • P260Do not breathe dust, fume, gas, mist, vapours or spray
  • P264Wash thoroughly after handling
  • P280Wear protective gloves, clothing and eye/face protection
  • P284Wear respiratory protection
  • P301IF SWALLOWED
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Flash point96 °C / 204.8 °F
Transport (UN / ADR)UN 3281 6.1 / PGII
Water hazard class (WGK, DE)3
Hazard codes (EU)T
Risk statements (R)23/24/25-40
Safety statements (S)23-26-36/37/39-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
12108-13-3
MDL number
MFCD00001426
PubChem substance
24859093
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is (Methylcyclopentadienyl)manganese(I) tricarbonyl used for?

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(Methylcyclopentadienyl)manganese(I) tricarbonyl is used as a reactant in organic synthesis, such as aldol addition reactions, and in materials science for doping semiconductor nanocrystals and preparing thin films like MnAs.

What are the CAS number and chemical formula?

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The CAS number is 12108-13-3, and the chemical formula is C5H4CH3Mn(CO)3.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies this compound as a research or technical grade chemical. We do not represent it as meeting USP, BP, or EP pharmacopoeia standards.

How should (Methylcyclopentadienyl)manganese(I) tricarbonyl be handled safely?

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This compound is hazardous and toxic. Handle with extreme care in a well-ventilated area or fume hood, wearing appropriate personal protective equipment including eyeshields, face shields, gloves, and a full-face or combination respirator (refer to safety data sheet for specifics). It is acutely toxic if swallowed, inhaled, or in contact with skin, and is suspected of causing cancer.

How is this chemical packed, shipped, and exported?

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This chemical is packed in accordance with international regulations for hazardous materials. Tech Serve Solutions exports globally, ensuring compliance with all transport and customs requirements.

How can I request a quote or sample?

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Please contact our sales team or use the online inquiry form to request a quote or a sample of (Methylcyclopentadienyl)manganese(I) tricarbonyl.

Need (Methylcyclopentadienyl)manganese(I) tricarbonyl in a specific grade or volume?