Germanium(IV) methoxide

CAS 992-91-6Ge(OCH3)4Catalysis & Inorganic

Germanium(IV) methoxide (CAS: 992-91-6; Formula: Ge(OCH3)4) is an organogermanium compound with a molecular weight of 196.78 g/mol. This colourless liquid serves as a valuable precursor in materials science and chemical synthesis. Its primary applications include its use as a promoting agent in oxidation reactions and its role in the preparation of sol-gel hybrid coatings for chromatographic applications.

IUPAC: Methyl germanate(IV),Tetramethoxygermanium

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Germanium(IV) methoxide (Ge(OCH3)4) — chemical structure, CAS 992-91-6; Chemistry, fine chemical supplied by Tech Serve Solutions

Chemical SynthesisGermaniumMaterials ScienceMicro/NanoElectronics

01 /Applications

Promoting Agent in Oxidation Reactions

Germanium(IV) methoxide acts as a promoting agent for vanadyl pyrophosphate-catalyzed oxidation reactions, contributing to enhanced catalytic efficiency in specific chemical transformations.

Sol-Gel Coatings for Chromatography

It is employed in the preparation of sol-gel hybrid organic-inorganic coatings, which are crucial for capillary microextension and gas chromatography (GC) applications, improving separation performance.

Precursor for Nanomaterials

This compound is utilised in the synthesis of advanced materials, such as gold nanoparticle templated germania nanoshells, highlighting its role in nanotechnology and materials innovation.

Synthesis of Organometallic Complexes

Germanium(IV) methoxide is a reagent in the preparation of specific organometallic structures, including metal(IV) β-cyclodextrin bucket wheel complexes.

02 /Properties

Molecular weight	196.78
Linear formula	Ge(OCH3)4
Form	liquid
Boiling point	66-67 °C/36 mmHg(lit.)
Density	1.325 g/mL at 25 °C(lit.)
Refractive index	n20/D 1.399(lit.)
Impurities tested	≤5% methyl alcohol
Melting point	−18 °C (dec.)(lit.)
Application	• Used as a promoting agent for vanadyl pyrophosphate-catalyzed oxidation reactions1• Used to prepare sol-gel hybrid organic-inorganic coatings for capillary microextension and gas chromatography (GC)2• For preparation of metal(IV) β-cyclodextrin bucket wheel complex3• Preparation of gold nanoparticle templated germania nanoshells4

03 /Safety & handling

GHS hazard pictogram: Flammable (GHS02) — Flammable

GHS hazard pictogram: Toxic (GHS06) — Toxic

GHS hazard pictogram: Health hazard (GHS08) — Health hazard

Danger

Hazard statements

H226Flammable liquid and vapour
H301Toxic if swallowed
H311Toxic in contact with skin
H315Causes skin irritation
H319Causes serious eye irritation
H331Toxic if inhaled
H335May cause respiratory irritation
H371May cause damage to organs

Precautionary statements

P260Do not breathe dust, fume, gas, mist, vapours or spray
P280Wear protective gloves, clothing and eye/face protection
P301IF SWALLOWED
P305IF IN EYES
P311Call a POISON CENTER or doctor

Flash point	41 °C / 105.8 °F
Transport (UN / ADR)	UN 1993C 3 / PGIII
Water hazard class (WGK, DE)	3
Hazard codes (EU)	T
Risk statements (R)	10-23/24/25-36/37/38-68/20/21/22
Safety statements (S)	26-36/37-45

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry

CAS number

992-91-6

MDL number

MFCD00014881

PubChem substance

24864668

05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Germanium(IV) methoxide used for?

Germanium(IV) methoxide is used as a promoting agent for vanadyl pyrophosphate-catalyzed oxidation reactions, in the preparation of sol-gel hybrid coatings for capillary microextension and gas chromatography, and for the synthesis of various germanium-containing complexes and nanomaterials.

What is the CAS number and formula for Germanium(IV) methoxide?

The CAS number for Germanium(IV) methoxide is 992-91-6, and its chemical formula is Ge(OCH3)4.

What grade and purity does Tech Serve Solutions supply?

Tech Serve Solutions supplies Germanium(IV) methoxide with a purity of ≤5% methyl alcohol. This product is supplied as a technical/research grade and is not represented as USP, BP, EP, or other pharmacopoeia grades.

What are the primary safety hazards associated with Germanium(IV) methoxide?

Germanium(IV) methoxide is a flammable liquid and vapour (H226). It is toxic if swallowed (H301), in contact with skin (H311), and if inhaled (H331). It can cause skin irritation (H315), serious eye irritation (H319), and may cause respiratory irritation (H335) and damage to organs (H371).

How is Germanium(IV) methoxide packed, shipped, and exported?

Germanium(IV) methoxide is classified as UN 1993, C3/PGIII for transport. Tech Serve Solutions ensures compliant packing and shipping for domestic and international export, adhering to all relevant regulations for hazardous materials.

How can I request a sample or a quote for Germanium(IV) methoxide?

To request a sample or a quote for Germanium(IV) methoxide, please contact our sales team through the website or by phone. Provide the product name, CAS number, and your required quantity for prompt assistance.