Ethylenebis(triphenylphosphine)platinum(0)
Ethylenebis(triphenylphosphine)platinum(0), identified by CAS number 12120-15-9 and the formula [(C6H5)3P]2Pt(H2C=CH2), is a platinum(0) complex with a molecular weight of 747.70. It functions as a nucleophilic metal species, readily undergoing ligand exchange with alkenes and alkynes. This compound serves as a valuable catalyst in hydrosilation reactions and as a reagent for oxidative addition to activated carbon-heteroatom bonds, making it significant in organometallic chemistry and synthesis.
![Ethylenebis(triphenylphosphine)platinum(0) ([(C6H5)3P]2Pt(H2C=CH2)) — chemical structure, CAS 12120-15-9; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F12120-15-9.png&w=3840&q=75)
Ligand Exchange Reactions
This platinum(0) complex acts as a nucleophilic metal species, facilitating ligand exchange reactions with unsaturated hydrocarbons such as alkenes and alkynes. This property is crucial for modifying metal coordination spheres in catalytic processes.
Hydrosilation Catalysis
It serves as an effective catalyst for hydrosilation reactions, a process involving the addition of a Si-H or B-H bond across an unsaturated organic molecule. This is widely applied in the synthesis of organosilicon compounds and fine chemicals.
Oxidative Addition Reagent
The compound is utilized as a reagent for oxidative addition reactions, particularly with activated carbon-heteroatom (C-X) bonds. This reactivity is fundamental in organometallic synthesis and the development of new chemical transformations.
| Molecular weight | 747.70 |
|---|---|
| Linear formula | [(C6H5)3P]2Pt(H2C=CH2) |
| Application | Nucleophilic metal species for ligand exchangewith alkenes and alkynes; catalysts for hydrosilation; reagent for oxidative addition to activated C-X bonds |
| Melting point | 129-132 °C (dec.)(lit.) |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26-37/39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Ethylenebis(triphenylphosphine)platinum(0) used for?
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Ethylenebis(triphenylphosphine)platinum(0) is used as a nucleophilic metal species for ligand exchange with alkenes and alkynes, as a catalyst for hydrosilation, and as a reagent for oxidative addition to activated C-X bonds.
What is the CAS number and chemical formula for this compound?
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The CAS number is 12120-15-9, and the chemical formula is [(C6H5)3P]2Pt(H2C=CH2).
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this chemical for research and laboratory purposes. The specific grade and purity are typically determined by the product specifications; please refer to the product's Certificate of Analysis for precise details. We do not represent this product as USP, BP, or EP grade.
What are the safety and handling considerations for Ethylenebis(triphenylphosphine)platinum(0)?
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This compound is classified as a Warning, with hazards including skin irritation (H315), eye irritation (H319), and respiratory irritation (H335). Appropriate personal protective equipment, including Eyeshields, Gloves, and a dust mask type N95 (US), should be used. Ensure adequate ventilation and avoid inhalation of dust.
How is Ethylenebis(triphenylphosphine)platinum(0) packed, shipped, and exported?
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Tech Serve Solutions adheres to international shipping regulations for the safe packaging, handling, and export of chemical compounds, ensuring compliance and product integrity throughout the supply chain.
How can I request a sample or quote for Ethylenebis(triphenylphosphine)platinum(0)?
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To request a sample or obtain a quote, please contact our sales department directly through the contact information provided on the Tech Serve Solutions website. Our team will be pleased to assist you with your inquiry.
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