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Bis(triphenylphosphine)rhodium(I) carbonyl chloride

CAS 13938-94-8[(C6H5)3P]2RhCl(CO)Catalysis & Inorganic

Bis(triphenylphosphine)rhodium(I) carbonyl chloride, CAS 13938-94-8, is a rhodium(I) complex with the linear formula [(C6H5)3P]2RhCl(CO). This compound, with a molecular weight of 690.94 g/mol, is primarily utilised as a catalyst in various chemical synthesis applications, particularly known for its role in cyclometallation reactions. Tech Serve Solutions supplies this high-purity chemical for research and industrial catalysis needs.

IUPAC
Chlorocarbonylbis(triphenylphosphine)rhodium(I),RhCl(CO)(PPh3)2,Rhodiumbis(triphenylphosphine) carbonyl chloride
Synonyms
Chlorocarbonylbis(triphenylphosphine)rhodium(I)Rhodium bis(triphenylphosphine) carbonyl chlorideRhCl(CO)(PPh3)2
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Bis(triphenylphosphine)rhodium(I) carbonyl chloride ([(C6H5)3P]2RhCl(CO)) — chemical structure, CAS 13938-94-8; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisRhodium
01 /Applications

Cyclometallation Reactions

This rhodium complex is specifically employed to facilitate cyclometallation processes. These reactions are crucial for forming metal-carbon bonds and are extensively studied in organometallic chemistry and catalysis.

Homogeneous Catalysis

As a rhodium-based catalyst, it can be applied in various homogeneous catalytic transformations. Its structure, featuring rhodium in a low oxidation state coordinated by phosphine ligands and carbon monoxide, enables participation in catalytic cycles.

Organometallic Synthesis

The compound serves as a valuable precursor or reagent in the synthesis of more complex organometallic compounds. Its well-defined coordination sphere allows for predictable reactivity in synthetic procedures.

02 /Properties
Molecular weight690.94
Linear formula[(C6H5)3P]2RhCl(CO)
Assay99.9%
ApplicationUsed for cyclometallation.1
Melting point224-227 °C (dec.)(lit.)
03 /Safety & handling
Protective equipmentEyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Water hazard class (WGK, DE)3

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
13938-94-8
MDL number
MFCD00044273
PubChem substance
24852243
Beilstein registry
4618896
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Bis(triphenylphosphine)rhodium(I) carbonyl chloride used for?

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Bis(triphenylphosphine)rhodium(I) carbonyl chloride is used for cyclometallation reactions and in various chemical synthesis applications as a rhodium-based catalyst.

What is the CAS number and formula for Bis(triphenylphosphine)rhodium(I) carbonyl chloride?

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The CAS number is 13938-94-8 and the linear formula is [(C6H5)3P]2RhCl(CO).

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Bis(triphenylphosphine)rhodium(I) carbonyl chloride with a minimum assay of 99.9%. This product is supplied for research and laboratory use and is not represented as USP, BP, EP, or pharmacopoeia grade.

How should Bis(triphenylphosphine)rhodium(I) carbonyl chloride be handled?

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Handling requires appropriate personal protective equipment, including eyeshields and gloves. A type N95 (US) or type P1 (EN143) respirator filter should be used. Refer to the Safety Data Sheet for comprehensive handling information.

Is Bis(triphenylphosphine)rhodium(I) carbonyl chloride a controlled substance?

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Based on the provided data, there is no indication that Bis(triphenylphosphine)rhodium(I) carbonyl chloride is a controlled substance.

How can I request a sample or quote for Bis(triphenylphosphine)rhodium(I) carbonyl chloride?

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To request a sample or a quotation, please contact the Tech Serve Solutions sales team through the website or by phone, providing the product name and CAS number.

How is this chemical packed and shipped?

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Tech Serve Solutions responsibly packs and ships chemicals according to international regulations. Specific packaging details will be provided upon request, and we are experienced in exporting globally.

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