Bis(trifluoromethane)sulfonimide
Bis(trifluoromethane)sulfonimide (CAS: 82113-65-3) is a potent chemical compound with the molecular formula (CF3SO2)2NH and a molecular weight of 281.15 g/mol. It is recognised for its utility as a strong non-nucleophilic acid and its role in various synthetic chemistry applications, particularly in fluorination processes. Available from Tech Serve Solutions, it serves as a valuable reagent in advanced chemical research and development.
- IUPAC
- Bis(trifluoromethanesulfonyl)amine,Bis(trifluoromethylsulfonyl)amine
- Synonyms
- Bis(trifluoromethanesulfonyl)amineBis(trifluoromethylsulfonyl)amine

Fluorination Reagent
This compound is employed as a reagent in organic synthesis for the introduction of trifluoromethanesulfonyl ('triflyl') groups. Its application is crucial in modifying the properties of molecules for specific chemical and pharmaceutical applications.
Chemical Synthesis
Bis(trifluoromethane)sulfonimide acts as a strong acid catalyst and a precursor in the synthesis of various complex organic molecules. It facilitates reactions requiring highly acidic or electrophilic conditions.
Electrolyte Additive Research
In research settings, compounds derived from bis(trifluoromethane)sulfonimide are explored for their potential use in advanced battery technologies, such as lithium-ion batteries, due to their electrochemical stability.
| Molecular weight | 281.15 |
|---|---|
| Linear formula | (CF3SO2)2NH |
| Assay | ≥95.0% (19F-NMR) |
| Grade | purum |
| Boiling point | 90-91 °C(lit.) |
| Melting point | 52-56 °C61-65 °C |

Hazard statements
- H314Causes severe skin burns and eye damage
Precautionary statements
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges61-65 °C |
|---|---|
| Transport (UN / ADR) | UN 3261 8 / PGI |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | C |
| Risk statements (R) | 14-34 |
| Safety statements (S) | 26-36/37/39-45 |
| Supplemental hazards | Reacts violently with water. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Bis(trifluoromethane)sulfonimide primarily used for?
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Bis(trifluoromethane)sulfonimide is primarily used in chemical synthesis as a fluorinating agent and as a strong acid catalyst. It is also utilised in research for modifying organic molecules and exploring applications in areas like electrolyte development.
What is the CAS number and chemical formula for Bis(trifluoromethane)sulfonimide?
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The CAS number for Bis(trifluoromethane)sulfonimide is 82113-65-3, and its linear chemical formula is (CF3SO2)2NH.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Bis(trifluoromethane)sulfonimide with a minimum assay of ≥95.0% (19F-NMR), specified as 'purum' grade. We do not represent this product as meeting USP, BP, or EP pharmacopoeia standards.
How should Bis(trifluoromethane)sulfonimide be handled safely?
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Bis(trifluoromethane)sulfonimide is classified as Dangerous (GHS05, Danger) and has hazard statement H314, indicating it causes severe skin burns and eye damage. It reacts violently with water. Appropriate personal protective equipment, including eyeshields, face shields, and chemical-resistant gloves, is essential. Handle in a well-ventilated area and avoid contact with water.
Is Bis(trifluoromethane)sulfonimide a controlled substance?
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The provided data does not indicate that Bis(trifluoromethane)sulfonimide is a controlled or scheduled substance.
How is Bis(trifluoromethane)sulfonimide packed and shipped?
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Bis(trifluoromethane)sulfonimide is shipped according to international regulations for hazardous materials (UN 3261, Class 8). Specific packaging details for export can be provided upon request.
How can I request a sample or quote for Bis(trifluoromethane)sulfonimide?
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To request a sample or obtain a quotation for Bis(trifluoromethane)sulfonimide, please contact our sales department through the website or via direct inquiry, providing your specific requirements.
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