2-Bromoisobutyric anhydride
2-Bromoisobutyric anhydride (CAS: 42069-15-8, Formula: C8H12Br2O3) is a chemical compound with a molecular weight of 315.99 g/mol. It is widely recognised as a potent initiator for Atom Transfer Radical Polymerization (ATRP), a controlled polymerization technique. This compound is essential in materials science and polymer science for synthesising polymers with controlled architectures and functionalities. Tech Serve Solutions supplies this reagent in powder form with 95% assay.
- IUPAC
- 2-Bromo-2-methylpropanoic anhydride,ATRP initiator

Atom Transfer Radical Polymerization (ATRP) Initiator
This compound serves as a highly effective initiator for ATRP, a widely used controlled radical polymerization method. It enables precise control over polymer chain growth, leading to well-defined polymer structures.
Polymer Synthesis
Used in the synthesis of various polymers, particularly those requiring controlled molecular weight and narrow polydispersity. Its application is crucial in developing advanced materials for diverse scientific and industrial purposes.
Materials Science Research
Facilitates the creation of novel polymeric materials with tailored properties. This is vital for advancements in fields such as nanotechnology, biomaterials, and advanced coatings.
| Molecular weight | 315.99 |
|---|---|
| Empirical formula | C8H12Br2O3 |
| Assay | 95% |
| Form | powder |
| Application | This is a highly effective initiator for atom transfer radical polymerization (ATRP). |
| Melting point | 56-60 °C |


Hazard statements
- H302Harmful if swallowed
- H314Causes severe skin burns and eye damage
Precautionary statements
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Transport (UN / ADR) | UN 3265 8 / PGII |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | C,Xn |
| Risk statements (R) | 22-34 |
| Safety statements (S) | 26-36/37/39-39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 2-Bromoisobutyric anhydride used for?
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2-Bromoisobutyric anhydride is primarily used as an initiator for Atom Transfer Radical Polymerization (ATRP), a method for controlled polymer synthesis. It is valuable in materials science and polymer science research.
What is the CAS number and chemical formula for 2-Bromoisobutyric anhydride?
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The CAS number is 42069-15-8, and the chemical formula is C8H12Br2O3.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies 2-Bromoisobutyric anhydride with an assay of 95%. This is a technical/research grade product, and TSS does not represent it as USP, BP, or EP grade.
What are the safety and handling precautions for this chemical?
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This compound is classified as Danger (GHS05, GHS07) and causes severe skin burns and eye damage (H314) and is harmful if swallowed (H302). Appropriate personal protective equipment, including gloves, eye protection, and protective clothing, must be worn. Handle in a well-ventilated area. Refer to the Safety Data Sheet (SDS) for comprehensive handling and emergency procedures.
Is 2-Bromoisobutyric anhydride a controlled substance?
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The provided data does not indicate that 2-Bromoisobutyric anhydride is a controlled substance.
How is this chemical shipped and exported?
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As per ADR classification, this product is shipped as UN 3265, Class 8, Packing Group II.
How can I request a quote or sample?
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Please contact our sales department through the website or by phone to request a quote or a sample of 2-Bromoisobutyric anhydride.
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