1,1′-Bis(dichlorophosphino)ferrocene
1,1′-Bis(dichlorophosphino)ferrocene (CAS 142691-70-1) is an organometallic compound with a molecular weight of 387.78 g/mol. This ferrocene derivative features two dichlorophosphine groups, making it a valuable precursor in organometallic synthesis and catalysis. It serves as a reactant for creating specialised ligands and bidentate phosphine compounds, finding applications in areas such as polymerization and homogeneous catalysis.
- Synonyms
- C10H8Cl4FeP2
Synthesis of Ferrocene-based Ligands
Utilised as a reactant in the synthesis of ferrocene-based bidentate phosphonite ligands. These ligands are crucial for rhodium(I)-catalyzed enantioselective hydroformylation reactions, enabling the production of chiral aldehydes.
Metallocene-Bridged Bisphosphaalkene Synthesis
Acts as a precursor for constructing metallocene-bridged bisphosphaalkene structures. This application is relevant in advanced materials science and coordination chemistry research.
Catalysis of Oligonuclear Complexes
Functions as a catalyst in the synthesis of oligonuclear heterometallic complexes. This role is significant in developing novel coordination compounds with unique electronic and catalytic properties.
| Molecular weight | 387.78 |
|---|---|
| Empirical formula | C10H8Cl4FeP2 |
| Assay | ≥96% |
| Application | Reactant for synthesis of:• Ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation1• Metallocene-bridged bisphosphaalkene2Catalyst for synthesis of oligonuclear heterometallic complexes3 |
| Melting point | 67-71 °C |
Hazard statements
- H314Causes severe skin burns and eye damage
Precautionary statements
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 1759 8 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | C |
| Risk statements (R) | 34 |
| Safety statements (S) | 26-36/37/39-45 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 1,1′-Bis(dichlorophosphino)ferrocene used for?
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1,1′-Bis(dichlorophosphino)ferrocene is primarily used as a reactant for synthesising ferrocene-based bidentate phosphonite ligands for rhodium(I)-catalyzed enantioselective hydroformylation and for creating metallocene-bridged bisphosphaalkenes. It also serves as a catalyst for the synthesis of oligonuclear heterometallic complexes.
What are the CAS number and formula for 1,1′-Bis(dichlorophosphino)ferrocene?
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The CAS number for 1,1′-Bis(dichlorophosphino)ferrocene is 142691-70-1, and its empirical formula is C10H8Cl4FeP2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies 1,1′-Bis(dichlorophosphino)ferrocene with an assay of ≥96%. We do not represent this product as USP, BP, EP, or any other pharmacopoeia grade.
How should 1,1′-Bis(dichlorophosphino)ferrocene be handled safely?
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1,1′-Bis(dichlorophosphino)ferrocene is classified as Danger (GHS05) and causes severe skin burns and eye damage (H314). Appropriate personal protective equipment, including eyeshields, faceshields, gloves, and suitable respiratory protection, must be used. Handle only in a well-ventilated area or under a fume hood. Consult the Safety Data Sheet for full handling and emergency procedures.
Is 1,1′-Bis(dichlorophosphino)ferrocene a controlled substance?
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The provided data does not indicate that 1,1′-Bis(dichlorophosphino)ferrocene is a controlled substance.
How is 1,1′-Bis(dichlorophosphino)ferrocene packed, shipped, and exported?
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1,1′-Bis(dichlorophosphino)ferrocene is packed and shipped according to international regulations for hazardous materials, identified as UN 1759, Hazard Class 8, Packing Group II. Tech Serve Solutions is experienced in exporting chemicals globally.
How can I request a sample or quote for 1,1′-Bis(dichlorophosphino)ferrocene?
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To request a sample or obtain a quote for 1,1′-Bis(dichlorophosphino)ferrocene, please contact our sales team through the TSS website or by calling our office.
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