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Tetrapropylammonium perruthenate

CAS 114615-82-6(CH3CH2CH2)4NRuO4Chemical Synthesis

Tetrapropylammonium perruthenate (CAS: 114615-82-6), with the molecular formula (CH3CH2CH2)4NRuO4 and a molecular weight of 351.43 g/mol, is a potent oxidizing agent. It is widely recognised as a highly effective and selective catalyst in organic synthesis, particularly for the oxidation of alcohols to carbonyl compounds under mild conditions. Its applications span various chemical synthesis pathways, making it a valuable reagent for research and development in organic chemistry.

IUPAC
TPAP
Synonyms
TPAP
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Tetrapropylammonium perruthenate ((CH3CH2CH2)4NRuO4) — chemical structure, CAS 114615-82-6; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisOthersOxidizing AgentsSynthetic Reagents
01 /Applications

Oxidation Catalyst in Organic Synthesis

Tetrapropylammonium perruthenate serves as an excellent catalyst for the oxidation of primary and secondary alcohols to aldehydes and ketones, respectively. It is often employed in conjunction with a co-oxidant, enabling efficient transformations under mild reaction conditions.

Selective Oxidation Reactions

Its high selectivity allows for targeted oxidation of specific functional groups within complex molecules. This is crucial in multi-step syntheses where preserving other functionalities is paramount.

Research and Development

This compound is a staple in academic and industrial research laboratories for exploring novel synthetic routes and developing new methodologies in organic chemistry.

02 /Properties
Molecular weight351.43
Linear formula(CH3CH2CH2)4NRuO4
Assay97%
Gradepurum
Storage temperature2-8°C
Melting point~160 °C (dec.)(lit.)
03 /Safety & handling
GHS hazard pictogram: Oxidising (GHS03)
Oxidising
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Danger

Hazard statements

  • H272May intensify fire; oxidiser
  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H335May cause respiratory irritation

Precautionary statements

  • P220Keep away from clothing and combustible materials
  • P261Avoid breathing dust, fume, gas or vapours
  • P305IF IN EYES
Protective equipmentEyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Transport (UN / ADR)UN 1479 5.1 / PGII
Water hazard class (WGK, DE)3
Hazard codes (EU)O,Xi
Risk statements (R)5-8-36/37/38
Safety statements (S)17-26-36

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
114615-82-6
MDL number
MFCD00074914
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Tetrapropylammonium perruthenate used for?

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Tetrapropylammonium perruthenate (TPAP) is primarily used as a highly effective catalyst for the selective oxidation of alcohols to aldehydes and ketones in organic synthesis.

What is the CAS number and formula for Tetrapropylammonium perruthenate?

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The CAS number for Tetrapropylammonium perruthenate is 114615-82-6, and its linear formula is (CH3CH2CH2)4NRuO4.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Tetrapropylammonium perruthenate with a purity of 97%, graded as 'purum'. TSS does not represent this product as USP, BP, or EP grade.

How should Tetrapropylammonium perruthenate be handled safely?

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Tetrapropylammonium perruthenate is a danger, an oxidizer, and a skin, eye, and respiratory irritant. Handle with appropriate personal protective equipment, including eyeshields, gloves, and a suitable respirator. Store away from combustible materials. Always consult the Safety Data Sheet (SDS) before use.

How is this chemical packed and shipped by TSS?

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Tetrapropylammonium perruthenate is packaged in accordance with UN 1479, 5.1/PGII regulations for safe transport. We export globally, adhering to all relevant shipping and hazardous materials regulations.

How can I request a quote or sample?

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To request a quote or a sample of Tetrapropylammonium perruthenate, please contact our sales team through the website or by calling us directly. Our team will be pleased to assist you.

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