Tetrapropylammonium perruthenate
Tetrapropylammonium perruthenate (CAS: 114615-82-6), with the molecular formula (CH3CH2CH2)4NRuO4 and a molecular weight of 351.43 g/mol, is a potent oxidizing agent. It is widely recognised as a highly effective and selective catalyst in organic synthesis, particularly for the oxidation of alcohols to carbonyl compounds under mild conditions. Its applications span various chemical synthesis pathways, making it a valuable reagent for research and development in organic chemistry.
- IUPAC
- TPAP
- Synonyms
- TPAP

Oxidation Catalyst in Organic Synthesis
Tetrapropylammonium perruthenate serves as an excellent catalyst for the oxidation of primary and secondary alcohols to aldehydes and ketones, respectively. It is often employed in conjunction with a co-oxidant, enabling efficient transformations under mild reaction conditions.
Selective Oxidation Reactions
Its high selectivity allows for targeted oxidation of specific functional groups within complex molecules. This is crucial in multi-step syntheses where preserving other functionalities is paramount.
Research and Development
This compound is a staple in academic and industrial research laboratories for exploring novel synthetic routes and developing new methodologies in organic chemistry.
| Molecular weight | 351.43 |
|---|---|
| Linear formula | (CH3CH2CH2)4NRuO4 |
| Assay | 97% |
| Grade | purum |
| Storage temperature | 2-8°C |
| Melting point | ~160 °C (dec.)(lit.) |


Hazard statements
- H272May intensify fire; oxidiser
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P220Keep away from clothing and combustible materials
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 1479 5.1 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | O,Xi |
| Risk statements (R) | 5-8-36/37/38 |
| Safety statements (S) | 17-26-36 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Tetrapropylammonium perruthenate used for?
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Tetrapropylammonium perruthenate (TPAP) is primarily used as a highly effective catalyst for the selective oxidation of alcohols to aldehydes and ketones in organic synthesis.
What is the CAS number and formula for Tetrapropylammonium perruthenate?
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The CAS number for Tetrapropylammonium perruthenate is 114615-82-6, and its linear formula is (CH3CH2CH2)4NRuO4.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Tetrapropylammonium perruthenate with a purity of 97%, graded as 'purum'. TSS does not represent this product as USP, BP, or EP grade.
How should Tetrapropylammonium perruthenate be handled safely?
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Tetrapropylammonium perruthenate is a danger, an oxidizer, and a skin, eye, and respiratory irritant. Handle with appropriate personal protective equipment, including eyeshields, gloves, and a suitable respirator. Store away from combustible materials. Always consult the Safety Data Sheet (SDS) before use.
How is this chemical packed and shipped by TSS?
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Tetrapropylammonium perruthenate is packaged in accordance with UN 1479, 5.1/PGII regulations for safe transport. We export globally, adhering to all relevant shipping and hazardous materials regulations.
How can I request a quote or sample?
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To request a quote or a sample of Tetrapropylammonium perruthenate, please contact our sales team through the website or by calling us directly. Our team will be pleased to assist you.
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