(S)-BINAPINE-rhodium complex

CAS 1046806-02-3C60H60BF4P2RhChemical Synthesis

(S)-BINAPINE-rhodium complex (CAS: 1046806-02-3), a chiral organometallic compound with the formula C60H60BF4P2Rh and a molecular weight of 1032.78 g/mol. This rhodium complex is a highly effective catalyst recognised for its role in asymmetric synthesis. It demonstrates excellent enantioselectivity and reactivity, particularly in the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates, making it a valuable reagent in the synthesis of chiral molecules.

IUPAC: [(S)-BINAPINE(cyclooctadiene)rhodium(I)] tetrafluoroborate

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(S)-BINAPINE-rhodium complex (C60H60BF4P2Rh) — chemical structure, CAS 1046806-02-3; Chemistry, fine chemical supplied by Tech Serve Solutions

Asymmetric SynthesisChemical SynthesisChiral CatalystsLigandsand Reagents

01 /Applications

Asymmetric Hydrogenation

(S)-BINAPINE-rhodium complex is a potent catalyst for the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates. It facilitates the stereoselective reduction of double bonds, yielding enantiomerically enriched products.

Chiral Synthesis

This rhodium complex serves as a key chiral catalyst in the synthesis of enantiopure compounds. Its application is crucial in producing chiral building blocks for pharmaceuticals and fine chemicals.

Ligand Development

As a component incorporating the BINAPINE ligand, it represents advanced chiral ligand design. Its performance highlights the utility of such ligands in transition metal catalysis for stereoselective transformations.

02 /Properties

Molecular weight	1032.78
Empirical formula	C60H60BF4P2Rh
Application	Demonstates excellent enantioselectivity and reactivity for the asymmetric hydrogenation of Z-β-aryl(β-acylamino)acrylates.1
Melting point	>300 °C

03 /Safety & handling

Protective equipment	Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Water hazard class (WGK, DE)	3

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry

CAS number

1046806-02-3

MDL number

MFCD07782007

05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is (S)-BINAPINE-rhodium complex used for?

(S)-BINAPINE-rhodium complex is primarily used as a catalyst in asymmetric synthesis, specifically for the enantioselective hydrogenation of Z-β-aryl(β-acylamino)acrylates.

What is the CAS number and molecular formula for (S)-BINAPINE-rhodium complex?

The CAS number is 1046806-02-3, and the molecular formula is C60H60BF4P2Rh.

What grade and purity does Tech Serve Solutions supply?

Tech Serve Solutions supplies (S)-BINAPINE-rhodium complex in research/technical grade. We do not represent it as USP/BP/EP or other pharmacopoeial grades unless explicitly stated.

How should (S)-BINAPINE-rhodium complex be handled?

Handle (S)-BINAPINE-rhodium complex with appropriate personal protective equipment, including eyeshields and gloves. A type N95 (US) or type P1 (EN143) respirator filter is recommended. Store in a well-ventilated area.

How is (S)-BINAPINE-rhodium complex shipped and exported?

Tech Serve Solutions expertly packs and exports fine chemicals globally, adhering to all relevant shipping regulations. Please contact us for specific export details.