Rhodium(III) acetylacetonate
Rhodium(III) acetylacetonate, identified by CAS number 14284-92-5, is a rhodium complex with the linear formula [CH₃COCH=C(O⁻)CH₃]₃Rh and a molecular weight of 400.23 g/mol. This solid compound serves as a highly effective catalyst, particularly in the hydrogenation of carboxylic acids when paired with group 6 or 7 metal carbonyls. It finds applications across catalysis, chemical synthesis, materials science, and micro/nanoelectronics.
- IUPAC
- 2,4-Pentanedione rhodium(III) derivative,Rh(acac)3
- Synonyms
- 2,4-Pentanedione rhodium(III) derivativeRh(acac)3
![Rhodium(III) acetylacetonate ([CH3COCH=C(O-)CH3]3Rh) — chemical structure, CAS 14284-92-5; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F14284-92-5.png&w=3840&q=75)
Catalysis
Rhodium(III) acetylacetonate is a potent catalyst for the hydrogenation of carboxylic acids. Its efficacy is notably enhanced when used in conjunction with group 6 or group 7 metal carbonyls, offering efficient chemical transformations in organic synthesis.
Chemical Synthesis
As a versatile rhodium precursor, it is employed in various organic synthesis reactions. Its defined structure and reactivity make it a valuable reagent for introducing rhodium into complex molecules or facilitating specific bond formations.
Materials Science
This compound can be utilised in materials science for the development of novel materials. Its properties may contribute to the synthesis of advanced materials with specific electronic or catalytic characteristics.
Micro/Nanoelectronics Precursor
Rhodium(III) acetylacetonate is suitable for use as a precursor in micro and nanoelectronics applications, potentially in deposition processes for creating thin films or nanostructures involving rhodium.
| Molecular weight | 400.23 |
|---|---|
| Linear formula | [CH3COCH=C(O-)CH3]3Rh |
| Assay | 97% |
| Form | solid |
| Application | Very effective catalyst for the hydrogenation of carboxylic acids when combined with group 6 or group 7 metal carbonyls.1 |
| Melting point | 263-264 °C(lit.) |
Hazard statements
- H302Harmful if swallowed
- H312Harmful in contact with skin
- H315Causes skin irritation
- H319Causes serious eye irritation
- H332Harmful if inhaled
- H335May cause respiratory irritation
- H361Suspected of damaging fertility or the unborn child
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xn |
| Risk statements (R) | 63-20/21/22-36/37/38 |
| Safety statements (S) | 26-36/37/39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Rhodium(III) acetylacetonate used for?
+
Rhodium(III) acetylacetonate is primarily used as a catalyst for the hydrogenation of carboxylic acids, often in combination with group 6 or 7 metal carbonyls. It also serves as a precursor in chemical synthesis, materials science, and micro/nanoelectronics applications.
What is the CAS number and formula for Rhodium(III) acetylacetonate?
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The CAS number for Rhodium(III) acetylacetonate is 14284-92-5, and its linear formula is [CH₃COCH=C(O⁻)CH₃]₃Rh.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Rhodium(III) acetylacetonate with an assay of 97%. We do not represent this product as USP, BP, EP, or pharmacopoeia grade.
How should Rhodium(III) acetylacetonate be handled safely?
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Rhodium(III) acetylacetonate is harmful if swallowed, in contact with skin, or if inhaled, and causes skin and eye irritation. It may also cause respiratory irritation and is suspected of damaging fertility or the unborn child. Handle with appropriate personal protective equipment, including a dust mask (type N95 US), eyeshields, and gloves, in a well-ventilated area.
How is Rhodium(III) acetylacetonate packed and shipped?
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Rhodium(III) acetylacetonate is carefully packed to ensure safe transit and is exported globally by Tech Serve Solutions.
How can I request a quote or sample for Rhodium(III) acetylacetonate?
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To request a quote or sample for Rhodium(III) acetylacetonate, please contact our sales team through the website.
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