Poly(ethylene glycol) divinyl ether
Poly(ethylene glycol) divinyl ether (CAS: 50856-26-3) is a homobifunctional crosslinker with the linear formula H₂C=CH(OCH₂CH₂)nOCH=CH₂ and an average molecular weight of Mn 250. This vinyl ether functionalised polyethylene glycol exhibits a density of 1.018 g/mL at 25 °C and a refractive index of n20/D 1.457. It is primarily utilised in polymer science and materials science for the synthesis of novel polymeric architectures and crosslinked networks.

Polymer Synthesis
Serves as a versatile monomer or crosslinker in the synthesis of various polymers, including hydrogels and functional resins. Its divinyl ether functionality allows for controlled polymerisation and network formation.
Materials Science
Enables the development of advanced materials by facilitating the creation of crosslinked polymer networks with tailored properties. Useful in the design of coatings, adhesives, and functional surfaces.
Surface Modification
Can be employed to modify surfaces, imparting specific characteristics such as hydrophilicity or reactivity. This is achieved through covalent attachment via its terminal vinyl ether groups.
| Linear formula | H2C=CH(OCH2CH2)nOCH=CH2 |
|---|---|
| Density | 1.018 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.457(lit.) |

Hazard statements
- H226Flammable liquid and vapour
| Protective equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 49 °C / 120.2 °F |
| Transport (UN / ADR) | UN 3271 3 / PGIII |
| Water hazard class (WGK, DE) | 3 |
| Risk statements (R) | 10 |
| Safety statements (S) | 16-36 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Mol Wt | average Mn 250 |
|---|
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Poly(ethylene glycol) divinyl ether used for?
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Poly(ethylene glycol) divinyl ether is used in polymer synthesis and materials science as a homobifunctional crosslinker for creating crosslinked polymer networks and modifying surfaces.
What is the CAS number and formula for Poly(ethylene glycol) divinyl ether?
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The CAS number is 50856-26-3, and its linear formula is H₂C=CH(OCH₂CH₂)nOCH=CH₂.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Poly(ethylene glycol) divinyl ether with an average molecular weight of Mn 250. This is a technical/research grade product, and TSS does not represent it as USP, BP, or EP grade.
How should Poly(ethylene glycol) divinyl ether be handled safely?
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Poly(ethylene glycol) divinyl ether is a flammable liquid and vapour (H226). Handle with appropriate personal protective equipment, including eyeshields, face shield, gloves, and a suitable respirator. Ensure adequate ventilation and keep away from heat, sparks, and open flames.
Is Poly(ethylene glycol) divinyl ether a controlled substance?
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The provided data does not indicate that Poly(ethylene glycol) divinyl ether is a controlled substance.
How is Poly(ethylene glycol) divinyl ether shipped and exported?
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Poly(ethylene glycol) divinyl ether is shipped under UN 3271, Class 3, Packing Group III. Tech Serve Solutions is experienced in global export procedures for chemical compounds.
How can I request a quote or sample for Poly(ethylene glycol) divinyl ether?
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To request a quote or sample, please contact the Tech Serve Solutions sales team through the website or by phone, providing the product name and CAS number (50856-26-3).
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