Fluoroantimonic acid
Fluoroantimonic acid (CAS 16950-06-4), with the formula HF · SbF5, is an exceptionally strong superacid. It is a colourless liquid with a density of 2.885 g/mL at 25 °C and a vapor pressure of 14 mmHg at 18 °C. Purified by triple-distillation, it is primarily used as a powerful reaction medium in organic synthesis, particularly for the preparation of specific organic salts.

Superacidic Reaction Medium
Fluoroantimonic acid serves as an extremely potent acidic medium for challenging chemical transformations. Its high acidity allows it to catalyse reactions that are not feasible with less potent acids.
Preparation of Alkylidene Oxonium Salts
This superacid is an excellent medium for the preparation of alkylidene oxonium salts. This application is crucial in specialised organic synthesis pathways where such intermediates are required.
Electronic Chemicals and Materials Science
As indicated by its classification within electronic chemicals and materials science, Fluoroantimonic acid may find applications in specialised research and development within these fields.
| Molecular weight | 236.76 |
|---|---|
| Linear formula | HF · SbF5 |
| Density | 2.885 g/mL at 25 °C(lit.) |
| Vapour pressure | 14 mmHg (18 °C) |
| Application | HF/SbF5 is an excellent medium for the preparation of alkylidene oxonium salts.1 |



Hazard statements
- H300Fatal if swallowed
- H314Causes severe skin burns and eye damage
- H411Toxic to aquatic life with long-lasting effects
Precautionary statements
- P260Do not breathe dust, fume, gas, mist, vapours or spray
- P264Wash thoroughly after handling
- P273Avoid release to the environment
- P280Wear protective gloves, clothing and eye/face protection
- P284Wear respiratory protection
- P301IF SWALLOWED
| Protective equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Transport (UN / ADR) | UN 2922 8/PG 2 |
| Water hazard class (WGK, DE) | 2 |
| Hazard codes (EU) | T+,C,N |
| Risk statements (R) | 26/27/28-35-51/53 |
| Safety statements (S) | 26-28-36/37/39-45-61 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Purified By | triple-distillation |
|---|
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Fluoroantimonic acid used for?
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Fluoroantimonic acid (CAS 16950-06-4, HF · SbF5) is principally used as a potent reaction medium in organic synthesis, notably for preparing alkylidene oxonium salts.
What are the CAS number and formula for Fluoroantimonic acid?
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The CAS number for Fluoroantimonic acid is 16950-06-4, and its formula is HF · SbF5.
What grade and purity does Tech Serve Solutions supply for Fluoroantimonic acid?
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Tech Serve Solutions supplies Fluoroantimonic acid purified by triple-distillation. We do not represent this product as USP, BP, or EP grade.
What are the primary safety hazards associated with Fluoroantimonic acid?
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Fluoroantimonic acid is extremely corrosive and toxic. It carries GHS hazards including acute toxicity (fatal if swallowed, in contact with skin, or if inhaled), and causes severe skin burns and eye damage. It is also toxic to aquatic life with long-lasting effects. Appropriate personal protective equipment, including full-face respirators and chemical-resistant gloves, is essential.
How is Fluoroantimonic acid typically packed, shipped, and exported?
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Fluoroantimonic acid is shipped as a UN 2922, Hazard Class 8, Packing Group II substance. Specific packaging and export procedures adhere to international regulations for hazardous materials.
How can I request a sample or obtain a quote for Fluoroantimonic acid?
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To request a sample or obtain a quote for Fluoroantimonic acid, please contact the Tech Serve Solutions sales team directly through our website or listed contact details.
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