Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I)
Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I) (CAS: 32627-01-3; Formula: C12H15O2Rh) is a rhodium complex with a molecular weight of 294.15 g/mol. Supplied by Tech Serve Solutions with an assay of 99%, this compound is primarily utilised as a catalyst in specialised organic synthesis. Its applications include facilitating the dehydrogenative germylation of olefins and the cyclotrimerisation of acetylenes, making it a valuable reagent for researchers in catalysis and inorganic chemistry.

Catalysis in Organic Synthesis
This rhodium complex serves as an effective catalyst for specific organic transformations. It is particularly noted for its role in the dehydrogenative germylation of olefins, a key reaction for forming carbon-germanium bonds.
Acetylene Cyclotrimerisation
Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I) is employed as a catalyst in the cyclotrimerisation of acetylenes. This reaction is crucial for synthesising substituted benzene rings from alkyne precursors.
Research in Inorganic Chemistry
As a well-defined organometallic compound, it is a subject of study within inorganic chemistry, offering insights into the reactivity and coordination behaviour of rhodium complexes.
| Molecular weight | 294.15 |
|---|---|
| Empirical formula | C12H15O2Rh |
| Assay | 99% |
| Storage temperature | −20°C |
| Application | Catalyst for:• Dehydrogenative germylation of olefins1• Cyclotrimerization of acetylenes2 |
| Melting point | 85-87 °C |
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I) used for?
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Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I) is used as a catalyst in organic synthesis, specifically for the dehydrogenative germylation of olefins and the cyclotrimerisation of acetylenes.
What is the CAS number and formula for Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I)?
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The CAS number is 32627-01-3 and the empirical formula is C12H15O2Rh.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I) with a minimum purity of 99%. This product is supplied for research and laboratory use and is not intended for human or veterinary use. We do not represent it as USP, BP, EP, or pharmacopoeia grade.
How should Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I) be handled and stored?
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According to the safety data, this compound has a WGK Germany classification of 3, indicating a high hazard to water. It should be stored at −20°C. Please consult the Safety Data Sheet for comprehensive handling instructions and appropriate personal protective equipment.
How is this chemical packed, shipped, and exported?
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Tech Serve Solutions specialises in the global supply and export of fine chemicals. Products are carefully packed according to international regulations for safe transport. Specific packaging details will be provided with your order confirmation.
How can I request a sample or quote for Dicarbonyl(pentamethylcyclopentadienyl)rhodium(I)?
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To request a sample or a quote, please contact our sales department via the website or email, providing the product name and CAS number (32627-01-3).
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