Dibromo[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II)
Dibromo[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) (CAS: 366488-99-5) is a chiral palladium(II) complex with the empirical formula C44H32Br2P2Pd and a molecular weight of 888.90 g/mol. This compound serves as a versatile catalyst in organic synthesis, particularly noted for its application in asymmetric reductive ammination reactions. Its specific chiral structure enables stereoselective transformations, making it valuable in the synthesis of complex molecules.
- Synonyms
- 366488-99-5, C44H32Br2P2Pd
![Dibromo[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) (C44H32Br2P2Pd) — chemical structure, CAS 366488-99-5; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F366488-99-5.png&w=3840&q=75)
Asymmetric Reductive Amination
This palladium complex is a highly effective chiral catalyst for asymmetric reductive amination reactions. It facilitates the stereoselective formation of chiral amines, which are crucial building blocks in pharmaceuticals and fine chemicals.
Homogeneous Palladium Catalysis
As a homogeneous palladium catalyst, it participates in a variety of catalytic cycles. Its BINAP-derived chiral ligand promotes enantioselectivity in transformations involving palladium.
Chiral Synthesis
The inherent chirality of the (S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl ligand makes this complex indispensable for asymmetric synthesis. It allows for the construction of stereogenic centres with high enantiomeric excess.
| Molecular weight | 888.90 |
|---|---|
| Empirical formula | C44H32Br2P2Pd |
| Assay | 97% |
| Application | Versatile chiral Pd catalyst for asymmetric reductive ammination. |
| Melting point | >300 °C |
Hazard statements
- H302Harmful if swallowed
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
| Water hazard class (WGK, DE) | 3 |
|---|---|
| Hazard codes (EU) | Xn |
| Risk statements (R) | 20/21/22-36/37/38 |
| Safety statements (S) | 26-36/37 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Dibromo[(S)-(−)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl]palladium(II) used for?
+
This compound is primarily used as a versatile chiral palladium catalyst for asymmetric reductive ammination reactions.
What is the CAS number and formula for this palladium complex?
+
The CAS number is 366488-99-5 and the empirical formula is C44H32Br2P2Pd.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies this product at an assay of 97%. This is a technical grade for research and synthesis; TSS does not represent it as USP, BP, or EP.
What are the safety considerations when handling this chemical?
+
This compound is classified with a 'Warning' signal word. It is harmful if swallowed, in contact with skin, or if inhaled (H302 + H312 + H332). It also causes skin irritation (H315), serious eye irritation (H319), and may cause respiratory irritation (H335). Handle with appropriate personal protective equipment in a well-ventilated area.
How is this chemical packed, shipped, and exported?
+
Tech Serve Solutions ensures secure packing for all chemicals. We are a specialist global supplier and exporter, adhering to all international shipping regulations for chemical compounds.
How can I request a sample or quote for this product?
+
Please use the 'Request a Quote' or 'Request a Sample' button on our website, or contact our sales team directly with your inquiry.
▶ Related products
Benzeneruthenium(II) chloride dimer
Ru2(C6H6)2Cl4
Catalysis & Inorganic
Benzoylferrocene
C17H14FeO
Catalysis & Inorganic
Benzyldiphenylphosphine
C6H5CH2P(C6H5)2
Catalysis & Inorganic
Beryllium
Be
Catalysis & Inorganic
Beryllium oxide
BeO
Catalysis & Inorganic![Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer — chemical structure, CAS 12257-42-0; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F12257-42-0.png&w=3840&q=75)
Bicyclo[2.2.1]hepta-2,5-diene-rhodium(I) chloride dimer
Catalysis & Inorganic
![Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluorobo — chemical structure, CAS 1228149-03-8; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1228149-03-8.png&w=3840&q=75)
Bis[(10,11-η)-5-[(11bS)-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-yl- κP4]-5H-dibenz[b,f]azepine]rhodium(I) tetrafluorobo
1-d:1′
Catalysis & Inorganic![Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride (C16H20ClN3Ni) — chemical structure, CAS 1033772-47-2; Catalysis & Inorganic, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F1033772-47-2.png&w=3840&q=75)
Bis[(2-dimethylamino)phenyl]amine nickel(II) chloride
C16H20ClN3Ni
Catalysis & Inorganic▶ Explore more
3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis
3-Methyl-1,5-pentanediol
Chemical Synthesis
3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis