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Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)

CAS 18987-59-2C18H24Cl2N2Pd2Catalysis & Inorganic

Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II), CAS 18987-59-2, is a palladium complex with a molecular weight of 552.14 g/mol. This compound serves as a versatile homogeneous catalyst, primarily employed in organic synthesis for various cross-coupling, carbonylation, and silylation reactions. Its specific structure facilitates efficient catalytic cycles, making it a valuable reagent for academic research and industrial applications requiring precise control over chemical transformations.

Synonyms
C18H24Cl2N2Pd2
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Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) (C18H24Cl2N2Pd2) — chemical structure, CAS 18987-59-2; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisHomogeneous Pd CatalystsPalladium
01 /Applications

Cross-Coupling Reactions

This palladium complex is an effective catalyst for Suzuki-Miyaura and Buchwald-Hartwig cross-coupling reactions, enabling the formation of carbon-carbon and carbon-heteroatom bonds, respectively.

Oxidative Transformations

It catalyses oxidative allylic C-H silylation and oxidative carbonylation reactions, facilitating the introduction of silicon-containing groups or carbonyl functionalities onto organic substrates.

Transesterification and Homologation

The compound finds application in catalysing transesterification reactions and in stereocontrolled homologation of carbon chain boronic esters using specific lithiated carbamates.

Mizoroki-Heck Reaction

As a homogeneous palladium catalyst, it is employed in the Mizoroki-Heck reaction for the vinylation of organic halides.

02 /Properties
Molecular weight552.14
Empirical formulaC18H24Cl2N2Pd2
Assay98%
ApplicationCatalyst for:• Oxidative allylic C-H silylation1• Transesterification reactions2• Suzuki-Miyaura cross-coupling reactions3• Stereocontrolled homologation of carbon chain boronic esters using Hoppe′s lithiated carbamates4• Oxidative carbonylation reactions5• Buchwald-Hartwig reactions6• Mizoroki-Heck reaction7
Melting point175 °C (dec.)(lit.)
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Warning

Hazard statements

  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H335May cause respiratory irritation

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P305IF IN EYES
Protective equipmentdust mask type N95 (US), Eyeshields, Gloves
Water hazard class (WGK, DE)3
Hazard codes (EU)Xi
Risk statements (R)36/37/38
Safety statements (S)26-37/39

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
18987-59-2
PubChem substance
24862423
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) used for?

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Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) is used as a homogeneous catalyst in various organic synthesis reactions, including Suzuki-Miyaura cross-coupling, Buchwald-Hartwig reactions, oxidative allylic C-H silylation, transesterification, oxidative carbonylation, and the Mizoroki-Heck reaction.

What is the CAS number and formula for Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II)?

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The CAS number is 18987-59-2 and the empirical formula is C18H24Cl2N2Pd2.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) at an assay of 98%. We do not represent this product as meeting any specific pharmacopoeia standards such as USP, BP, or EP.

How should Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) be handled?

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Handle with appropriate personal protective equipment, including a dust mask (N95 type US), eyeshields, and gloves. Ensure adequate ventilation. Avoid breathing dust. This compound may cause skin, eye, and respiratory irritation.

Is Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) a controlled substance?

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The provided safety data does not indicate that Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II) is a controlled or scheduled substance.

How is this chemical packed, shipped, and exported?

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Tech Serve Solutions carefully packs and ships chemicals globally, adhering to all relevant regulations for hazardous materials. Specific packing details are available upon request.

How can I request a sample or quote for this product?

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To request a sample or quote for Di-μ-chlorobis[2-[(dimethylamino)methyl]phenyl-C,N]dipalladium(II), please contact our sales department through the website or by phone, providing your specific requirements.

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