Chlorosulfonic acid
Chlorosulfonic acid (CAS 7790-94-5, ClSO3H) is a highly reactive inorganic acid. It is a colourless to pale yellow fuming liquid, known for its strong corrosive properties and its ability to react violently with water. This potent chemical is primarily employed as a versatile reagent in organic synthesis, particularly for the introduction of sulfonyl chloride groups, and in the production of various organic compounds.

Sulfonating Agent
Chlorosulfonic acid is a powerful sulfonating agent, widely used in organic chemistry to introduce the $-\text{SO}_2\text{Cl}$ group into aromatic compounds. This process is crucial for synthesizing pharmaceuticals, dyes, and detergents.
Detergent Intermediate
It serves as a key intermediate in the manufacture of detergents and surfactants. The reactions involving chlorosulfonic acid facilitate the creation of molecules with desirable cleaning properties.
Chemical Synthesis Reagent
This compound is a versatile reagent utilized in a broad range of chemical syntheses, including the preparation of sulfonic acids, sulfonyl halides, and other sulfur-containing organic molecules.
Dehydrating Agent
In certain specific applications, chlorosulfonic acid can act as a dehydrating agent, although its highly reactive nature requires careful control and specialized handling.
| Molecular weight | 116.52 |
|---|---|
| Linear formula | ClSO3H |
| Assay | 99% |
| Boiling point | 151-152 °C/755 mmHg(lit.) |
| Density | 1.753 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.433(lit.) |
| Vapour pressure | 1 mmHg (25 °C)3.3 mmHg (37.7 °C) |
| Vapour density | 4 (vs air) |
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Chlorosulfonic acid used for?
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Chlorosulfonic acid is predominantly used as a sulfonating agent in organic synthesis, for producing detergents, and as a general synthetic reagent for creating sulfur-containing organic compounds.
What is the CAS number and formula for Chlorosulfonic acid?
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The CAS number for Chlorosulfonic acid is 7790-94-5, and its linear formula is ClSO3H.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Chlorosulfonic acid with an assay of 99%. We do not represent this product as USP, BP, or EP grade.
What are the safety and handling considerations for Chlorosulfonic acid?
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Chlorosulfonic acid is highly corrosive and reacts violently with water, producing hazardous fumes. Handle with extreme care in a well-ventilated area, using appropriate personal protective equipment (P261, P280, P305 + P351 + P338, P310).
How is Chlorosulfonic acid packed, shipped, and exported?
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Chlorosulfonic acid is carefully packed according to international safety standards for hazardous materials. Tech Serve Solutions has extensive experience in exporting chemicals worldwide.
How can I request a sample or quote for Chlorosulfonic acid?
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To request a sample or a quote for Chlorosulfonic acid, please contact our sales team through the website or by phone.
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