Carbonyldihydridotris(triphenylphosphine)ruthenium(II)
Carbonyldihydridotris(triphenylphosphine)ruthenium(II) (CAS: 25360-32-1), with the formula [(C6H5)3P]3Ru(CO)H2 and a molecular weight of 919.79 g/mol, is a ruthenium-based organometallic compound. It serves as a versatile catalyst in organic synthesis, particularly noted for its utility in C-H activation, oxidation reactions, and cyclization processes. This compound is supplied by Tech Serve Solutions for research and development purposes.
- IUPAC
- Dihydridocarbonyltris(triphenylphosphine)ruthenium
- Synonyms
- Dihydridocarbonyltris(triphenylphosphine)ruthenium
![Carbonyldihydridotris(triphenylphosphine)ruthenium(II) ([(C6H5)3P]3Ru(CO)H2) — chemical structure, CAS 25360-32-1; Chemistry, fine chemical supplied by Tech Serve Solutions](/_next/image?url=https%3A%2F%2Fpub-f4d920c906024441a773a96f7098e551.r2.dev%2Fimages%2Fproducts%2F25360-32-1.png&w=3840&q=75)
C-H Activation Catalysis
This ruthenium complex is employed as a catalyst in directed C-H activation reactions, facilitating the formation of new carbon-carbon bonds. Its effectiveness has been documented in various synthetic methodologies.
Oxidation Reactions
It acts as a catalyst for the oxidation of primary alcohols to their corresponding methyl esters. This transformation is a key step in the synthesis of various organic compounds.
Pyrrole Synthesis
The compound catalyzes the conversion of 1,4-alkynediols into pyrroles. Pyrroles are important heterocyclic compounds with applications in pharmaceuticals and materials science.
Rearrangement Reactions
Carbonyldihydridotris(triphenylphosphine)ruthenium(II) is utilized as a catalyst for the rearrangement of oximes into amides, offering a pathway to valuable amide products.
Enyne Cyclization
This ruthenium catalyst plays a role in promoting enyne cyclization reactions, enabling the synthesis of cyclic organic structures.
| Molecular weight | 919.79 |
|---|---|
| Linear formula | [(C6H5)3P]3Ru(CO)H2 |
| Application | • Catalyst for conversion of 1,4-alkynediols into pyrroles1 • Catalyst for oxidation of primary alcohols to methyl esters2 • Catalyst for rearrangement of oximes to amides3 • Catalyst for C-C coupling via directed C-H activation4,5 • Catalyst for enyne cyclization6 |
| Melting point | 161-163 °C(lit.) |
Hazard statements
- H302Harmful if swallowed
- H312Harmful in contact with skin
- H332Harmful if inhaled
Precautionary statements
- P280Wear protective gloves, clothing and eye/face protection
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xn |
| Risk statements (R) | 20/21/22 |
| Safety statements (S) | 36 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Carbonyldihydridotris(triphenylphosphine)ruthenium(II) used for?
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Carbonyldihydridotris(triphenylphosphine)ruthenium(II) is primarily used as a catalyst in organic synthesis for various transformations, including C-H activation, oxidation of alcohols, pyrrole synthesis, oxime rearrangement, and enyne cyclization.
What is the CAS number and chemical formula for this compound?
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The CAS number is 25360-32-1, and the chemical formula is [(C6H5)3P]3Ru(CO)H2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies this chemical for research and development purposes. The specific grade and purity are available upon request. TSS does not represent this product as USP, BP, EP, or any pharmacopoeia grade.
What are the safety considerations when handling Carbonyldihydridotris(triphenylphosphine)ruthenium(II)?
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This compound is classified with GHS07 symbol and a 'Warning' signal word. It carries hazard statements H302 (Harmful if swallowed), H312 (Harmful in contact with skin), and H332 (Harmful if inhaled). Appropriate personal protective equipment, including a dust mask type N95 (US), eyeshields, and gloves, should be worn. Handle in a well-ventilated area.
How is Carbonyldihydridotris(triphenylphosphine)ruthenium(II) packed and exported?
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Tech Serve Solutions handles the packing and export of chemicals with professional care, adhering to all necessary regulations for international shipment. Specific packaging details can be provided upon inquiry.
How can I request a quote or sample?
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To request a quote or a sample of Carbonyldihydridotris(triphenylphosphine)ruthenium(II), please contact our sales department through the website or by phone.
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