Bromoiodomethane
Bromoiodomethane (CAS: 557-68-6, BrCH2I) is a dense, halogenated hydrocarbon with a molecular weight of 220.84 g/mol. As a versatile organic building block, it serves as a crucial reactant in various synthetic organic chemistry applications. Its key uses include facilitating carbene insertion reactions and participation in studies of ultrafast photodissociation, making it valuable for research and development in chemical synthesis.

Carbene Insertion Reactions
Bromoiodomethane acts as an effective precursor for generating carbenes. These reactive intermediates are then employed in insertion reactions to introduce a methylene unit into various chemical structures, enabling complex molecule synthesis.
Ultrafast Photodissociation Studies
This compound is utilised in research to investigate the dynamics of ultrafast photodissociation. Studying how Bromoiodomethane breaks apart upon light absorption provides insights into fundamental chemical bond cleavage processes.
Organic Synthesis Reagent
As a dihaloalkane, Bromoiodomethane is a useful building block in organic synthesis. It can undergo nucleophilic substitution reactions at either halogen, offering synthetic flexibility for creating diverse organic compounds.
| Molecular weight | 220.84 |
|---|---|
| Linear formula | BrCH2I |
| Assay | 97% |
| Boiling point | 138-141 °C(lit.) |
| Density | 2.93 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.6382(lit.) |
| Contains / stabiliser | copper as stabilizer |
| Application | Reactant for:• Carbene insertion reactions1• Ultrafast photodissociation2 |


Hazard statements
- H315Causes skin irritation
- H318Causes serious eye damage
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
| Protective equipment | Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 37/38-41 |
| Safety statements (S) | 26-36/39 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Bromoiodomethane used for?
+
Bromoiodomethane is primarily used as a reactant in carbene insertion reactions and in studies of ultrafast photodissociation, serving as a versatile building block in organic synthesis.
What are the CAS number and formula for Bromoiodomethane?
+
The CAS number for Bromoiodomethane is 557-68-6, and its linear formula is BrCH2I.
What grade and purity does Tech Serve Solutions supply?
+
Tech Serve Solutions supplies Bromoiodomethane with an assay of 97%. This product is supplied for laboratory and research purposes and is not represented as USP, BP, EP, or any other pharmacopoeia grade.
How should Bromoiodomethane be handled safely?
+
Bromoiodomethane is classified as Dangerous (GHS05, GHS07) and can cause skin irritation (H315), serious eye damage (H318), and respiratory irritation (H335). Always use appropriate personal protective equipment, including eyeshields, gloves, and a suitable respirator, and handle in a well-ventilated area.
How is Bromoiodomethane packed and shipped?
+
Bromoiodomethane is carefully packed according to international shipping regulations for hazardous chemicals. Tech Serve Solutions can export this product globally. Please contact us for specific shipping details and requirements.
How can I request a sample or quote for Bromoiodomethane?
+
To request a sample or a quote for Bromoiodomethane, please contact our sales team directly through our website or by phone, providing your specific requirements and delivery information.
▶ Related products

1-(2-Fluorobenzyl)piperazine
C11H15FN2
Chemical Synthesis
1-(2-Fluorophenyl)biguanide hydrochloride
Chemical Synthesis

1-(2-Fluorophenyl)cyclopropanecarboxylic acid
C10H9FO2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine
C10H13FN2
Chemical Synthesis
1-(2-Fluorophenyl)piperazine monohydrochloride
C10H13FN2 · HCl
Chemical Synthesis
1-(2-Furoyl)-1H-benzotriazole
C11H7N3O2
Chemical Synthesis
1-(2-Furoyl)piperazine
C9H12N2O2
Chemical Synthesis
1-(2-Hydroxy-5-methylphenyl)-3-phenyl-1,3-propanedione
Chemical Synthesis
▶ Explore more

3-Methyl-1,5-di-p-tolyl-1,4-pentazadiene
Chemical Synthesis

3-Methyl-1,5-pentanediol
Chemical Synthesis

3-Methyl-1-(2-methylphenyl)-1H-pyrazol-5-amine
C11H13N3
Chemical Synthesis
3-Methyl-1-(3′-sulfoamidophenyl)-5-pyrazolone
C10H11N3O3S
Chemical Synthesis