5-Hexenylzinc bromide solution
5-Hexenylzinc bromide solution (CAS 226570-65-6) is an organozinc halide, supplied as a 0.5 M solution in THF with a molar mass of 228.45 g/mol. This reagent is valuable in organic synthesis, particularly for carbon-carbon bond formation through cross-coupling reactions. Its reactivity profile makes it a useful building block in the synthesis of complex organic molecules, including pharmaceuticals and fine chemicals.

Organozinc Reagent in Cross-Coupling
5-Hexenylzinc bromide serves as a versatile nucleophile in various transition-metal-catalyzed cross-coupling reactions, enabling the formation of new carbon-carbon bonds.
Synthesis of Complex Organic Molecules
Its incorporation into synthetic strategies facilitates the construction of intricate molecular architectures relevant to pharmaceutical intermediates and advanced materials.
Alkylation and Functionalization
This organozinc compound can be employed for the selective alkylation of various electrophiles, introducing the hexenyl moiety into target structures.
| Molecular weight | 228.45 |
|---|---|
| Linear formula | H2C=CH(CH2)4ZnBr |
| Density | 0.978 g/mL at 25 °C |
| Concentration | 0.5 M in THF |
| Storage temperature | 2-8°C |



Hazard statements
- H225Highly flammable liquid and vapour
- H319Causes serious eye irritation
- H335May cause respiratory irritation
- H351Suspected of causing cancer
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P261Avoid breathing dust, fume, gas or vapours
- P281Use personal protective equipment as required
- P305IF IN EYES
| Flash point | -17 °C / 1.4 °F |
|---|---|
| Transport (UN / ADR) | UN 2924 8(3) / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,Xn |
| Risk statements (R) | 11-14-19-36/37-40 |
| Safety statements (S) | 16-26-36/37 |
| Supplemental hazards | May form explosive peroxides. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is 5-Hexenylzinc bromide solution used for?
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5-Hexenylzinc bromide solution is primarily used as an organozinc reagent in organic synthesis for carbon-carbon bond formation via cross-coupling reactions and for selective alkylation.
What is the CAS number and formula for 5-Hexenylzinc bromide solution?
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The CAS number is 226570-65-6, and its linear formula is H₂C=CH(CH₂)₄ZnBr.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies 5-Hexenylzinc bromide solution at a concentration of 0.5 M in THF. We do not represent this product as USP, BP, or EP grade; it is suitable for research and chemical synthesis applications.
How should 5-Hexenylzinc bromide solution be handled safely?
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This solution is a flammable liquid and vapour (H225), causes serious eye irritation (H319), and may cause respiratory irritation (H335). It is also suspected of causing cancer (H351) and may form explosive peroxides. Handle in a well-ventilated area, away from ignition sources, using appropriate personal protective equipment.
How is 5-Hexenylzinc bromide solution shipped?
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5-Hexenylzinc bromide solution is shipped under UN 2924, Hazard Class 8 (Corrosive) with subsidiary risk 3 (Flammable Liquid), Packing Group II.
How can I request a quote or sample?
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To request a quote or sample of 5-Hexenylzinc bromide solution, please contact our sales team through the Tech Serve Solutions website or by calling our main office.
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