Tech Serve Solutions

2-Methoxypropene

CAS 116-11-0CH2=C(CH3)OCH3Chemical Synthesis

2-Methoxypropene (CAS: 116-11-0), with the chemical formula CH2=C(CH3)OCH3 and a molecular weight of 72.11 g/mol, is a valuable reagent in organic synthesis. It is primarily utilised for the protection of adjacent hydroxyl groups, notably in inositols to form bisacetonides, and for the derivatisation of 1,2-diols. Its specific reactivity makes it an important tool in multi-step chemical processes.

IUPAC
Isopropenyl methyl ether
Synonyms
Isopropenyl methyl ether
Email us
2-Methoxypropene (CH2=C(CH3)OCH3) — chemical structure, CAS 116-11-0; Chemistry, fine chemical supplied by Tech Serve Solutions
Chemical SynthesisOthersSynthetic Reagents
01 /Applications

Protection of Hydroxyl Groups

2-Methoxypropene serves as an effective reagent for protecting adjacent hydroxyl functionalities in molecules such as inositols, forming stable bisacetonide derivatives. This protection strategy is crucial in multi-step synthesis to prevent unwanted side reactions.

Derivatisation of Diols

This compound is employed for the derivatisation of 1,2-diols. By reacting with these vicinal diols, it facilitates their modification, which can be useful for analytical purposes or for directing further chemical transformations.

Synthetic Reagent

As a versatile synthetic reagent, 2-Methoxypropene is used in various organic synthesis pathways. Its role in protecting functional groups aids in complex molecule construction and fine chemical production.

02 /Properties
Molecular weight72.11
Linear formulaCH2=C(CH3)OCH3
Assay97%
Boiling point34-36 °C(lit.)
Density0.753 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.382(lit.)
Vapour pressure27.96 psi (55 °C)8.28 psi (20 °C)
Autoignition temp374 °F
Storage temperature2-8°C
ApplicationUsed to protect adjacent hydroxyls in inositols as bisacetonides,1 and 1,2-diols in general.2
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Danger

Hazard statements

  • H224Extremely flammable liquid and vapour
  • H302Harmful if swallowed

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
Protective equipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Flash point-29 °C / -20.2 °F
Transport (UN / ADR)UN 1993A 3 / PGI
Water hazard class (WGK, DE)1
Hazard codes (EU)F+,Xn
Risk statements (R)12-19-22
Safety statements (S)3-7/9-16-29-33
Supplemental hazardsMay form explosive peroxides.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
116-11-0
MDL number
MFCD00014929
PubChem substance
24850352
Beilstein registry
1734635
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is 2-Methoxypropene used for?

+

2-Methoxypropene is used to protect adjacent hydroxyl groups in molecules like inositols, forming bisacetonides, and is also used for the derivatisation of 1,2-diols in organic synthesis.

What is the CAS number and formula for 2-Methoxypropene?

+

The CAS number for 2-Methoxypropene is 116-11-0, and its chemical formula is CH2=C(CH3)OCH3.

What grade and purity does Tech Serve Solutions supply?

+

Tech Serve Solutions supplies 2-Methoxypropene with an assay of 97%. This product is supplied for research and laboratory use and is not represented as USP, BP, EP, or any other pharmacopoeia grade.

How should 2-Methoxypropene be handled safely?

+

2-Methoxypropene is highly flammable (H224) and harmful if swallowed (H302). It may also form explosive peroxides. Handle in a well-ventilated area, away from ignition sources, and wear appropriate personal protective equipment including eyeshields, gloves, and a suitable respirator.

How is 2-Methoxypropene packed, shipped, and exported?

+

2-Methoxypropene is stored at 2-8°C. Shipping and export are handled in accordance with all applicable international regulations for hazardous materials, including flammable liquids.

How can I request a sample or a quote for 2-Methoxypropene?

+

To request a sample or a quote, please contact our sales team through the website or by phone, providing your specific requirements and shipping details.

Need 2-Methoxypropene in a specific grade or volume?