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(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)

CAS 361346-80-7C32H38CoN2O4Chemical Synthesis

(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) (CAS 361346-80-7) is an organometallic compound with the molecular formula C32H38CoN2O4 and a molecular weight of 573.59. This chiral cobalt complex serves as a valuable catalyst in asymmetric synthesis, facilitating enantioselective reductions and cycloaddition reactions. Its precise stereochemical properties make it a key reagent for producing chiral molecules.

IUPAC
(R,R)-AMAC
Synonyms
2-dimesitylethylenediaminato cobalt(II)361346-80-7C32H38CoN2O4
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(1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) (C32H38CoN2O4) — chemical structure, CAS 361346-80-7; Chemistry, fine chemical supplied by Tech Serve Solutions
Asymmetric SynthesisChemical SynthesisChiral CatalystsLigandsand ReagentsReduction
01 /Applications

Enantioselective Ketone Reduction

This cobalt complex acts as a chiral catalyst for the enantioselective reduction of ketones, enabling the synthesis of chiral alcohols with high optical purity.

Hetero Diels-Alder Reactions

It is employed as a catalyst in hetero Diels-Alder reactions, contributing to the stereoselective construction of cyclic organic molecules.

1,3-Dipolar Cycloaddition Reactions

The compound facilitates 1,3-dipolar cycloaddition reactions, offering a pathway for the stereocontrolled formation of heterocyclic compounds.

Carbonylene Reactions

This catalyst is also utilized in carbonylene reactions, expanding its utility in complex organic synthesis.

02 /Properties
Molecular weight573.59
Empirical formulaC32H38CoN2O4
Assay≥97%
Optical activity[α]/D 291°, c = 0.1 in chloroform
ApplicationCatalyst used for the enantioselective reduction of ketones, hetero Diels-Alder reaction, carbonylene reaction, 1,3-dipolar cycloaddition9
Melting point246-250 °C
03 /Safety & handling
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Warning

Hazard statements

  • H302Harmful if swallowed
  • H312Harmful in contact with skin
  • H315Causes skin irritation
  • H319Causes serious eye irritation
  • H332Harmful if inhaled
  • H335May cause respiratory irritation

Precautionary statements

  • P261Avoid breathing dust, fume, gas or vapours
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
Protective equipmentdust mask type N95 (US), Eyeshields, Gloves
Water hazard class (WGK, DE)2
Hazard codes (EU)Xn
Risk statements (R)20/21/22-36/37/38
Safety statements (S)22-24/25-36/37/39

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
361346-80-7
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is (1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) used for?

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This compound is primarily used as a catalyst in asymmetric synthesis, including the enantioselective reduction of ketones, hetero Diels-Alder reactions, carbonylene reactions, and 1,3-dipolar cycloaddition reactions.

What is the CAS number and formula for this product?

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The CAS number is 361346-80-7, and its empirical formula (Hill notation) is C32H38CoN2O4.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies this product with an assay of ≥97%. We do not represent this product as USP, BP, EP, or other pharmacopoeial grades.

What are the safety precautions when handling this chemical?

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Handle with appropriate personal protective equipment including a dust mask (N95), eyeshields, and gloves. Avoid breathing dust and ensure adequate ventilation. This compound is classified with GHS07 signal word 'Warning' due to hazards including H302, H312, H315, H319, H332, and H335.

How is this chemical packed, shipped, and exported?

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Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals. Specific packing and shipping details are provided upon inquiry, adhering to all relevant international regulations.

How can I request a sample or a quote for this product?

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Please contact our sales team directly via our website or by phone to request a sample or a formal quotation.

Need (1R,2R)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) in a specific grade or volume?