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1-Propenylmagnesium bromide solution

CAS 14092-04-7CH3CH=CHMgBrChemical Synthesis

1-Propenylmagnesium bromide solution (CAS 14092-04-7), with the linear formula CH3CH=CHMgBr and a molecular weight of 145.28, is an organometallic reagent supplied by Tech Serve Solutions as a 0.5 M solution in Tetrahydrofuran (THF). This compound is a reactive Grignard reagent, valuable in organic synthesis for introducing the 1-propenyl group into molecules. Its handling requires strict adherence to safety protocols due to its flammable and water-reactive nature.

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1-Propenylmagnesium bromide solution (CH3CH=CHMgBr) — chemical structure, CAS 14092-04-7; Chemistry, fine chemical supplied by Tech Serve Solutions
AlkenylChemical SynthesisGrignard ReagentsOrganometallic Reagents
01 /Applications

Organic Synthesis Intermediate

As a Grignard reagent, 1-Propenylmagnesium bromide is employed to form new carbon-carbon bonds. It is used to introduce the 1-propenyl moiety into various organic substrates, facilitating the construction of more complex molecular architectures.

Preparation of Alkenyl Compounds

This reagent serves as a key building block in the synthesis of diverse alkenyl-containing compounds. These can include pharmaceuticals, agrochemicals, and materials with specific electronic or optical properties.

Organometallic Chemistry Research

Researchers utilise 1-Propenylmagnesium bromide in studies involving organometallic reactions and mechanisms. Its specific reactivity profile allows for the exploration of new synthetic pathways and the development of novel chemical transformations.

02 /Properties
Molecular weight145.28
Linear formulaCH3CH=CHMgBr
Boiling point65 °C
Density0.95 g/mL at 25 °C
Concentration0.5 M in THF
Storage temperature2-8°C
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Danger

Hazard statements

  • H225Highly flammable liquid and vapour
  • H260In contact with water releases flammable gases
  • H314Causes severe skin burns and eye damage
  • H335May cause respiratory irritation

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P223Do not allow contact with water
  • P231Handle under inert gas
  • P261Avoid breathing dust, fume, gas or vapours
  • P370In case of fire
  • P422
Protective equipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
Flash point-20 °C / -4 °F
Transport (UN / ADR)UN 3399 4.3/PG 1
Water hazard class (WGK, DE)3
Hazard codes (EU)F,C
Risk statements (R)11-14/15-19-34-37
Safety statements (S)16-26-36/37/39-43-45
Supplemental hazardsMay form explosive peroxides., Reacts violently with water.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
14092-04-7
MDL number
MFCD00209610
PubChem substance
24866259
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is 1-Propenylmagnesium bromide solution used for?

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1-Propenylmagnesium bromide solution is used as a Grignard reagent in organic synthesis for introducing the 1-propenyl group and constructing carbon-carbon bonds, particularly in the preparation of alkenyl compounds.

What is the CAS number and formula for 1-Propenylmagnesium bromide solution?

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The CAS number is 14092-04-7, and the linear formula is CH3CH=CHMgBr.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies 1-Propenylmagnesium bromide solution at a concentration of 0.5 M in THF. TSS does not represent this product as USP/BP/EP; it is supplied for technical and research purposes.

How should 1-Propenylmagnesium bromide solution be handled safely?

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This solution is highly flammable and reacts violently with water, potentially forming explosive peroxides. Handle under an inert atmosphere, away from ignition sources, and use appropriate personal protective equipment, including face shields, respirators, gloves, and goggles.

How is 1-Propenylmagnesium bromide solution shipped and exported?

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1-Propenylmagnesium bromide solution is classified under UN 3399, Hazard Class 4.3, Packing Group I. It is shipped and exported adhering to all relevant dangerous goods regulations for flammable solids or substances, dangerous when wet.

How can I request a sample or quote for 1-Propenylmagnesium bromide solution?

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To request a sample or obtain a quote for 1-Propenylmagnesium bromide solution, please contact the Tech Serve Solutions sales team via our website or listed contact details.

Need 1-Propenylmagnesium bromide solution in a specific grade or volume?