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Titanium(IV) chloride tetrahydrofuran complex

CAS 31011-57-1TiCl4 · 2THFAcids & Bases

Titanium(IV) chloride tetrahydrofuran complex (CAS 31011-57-1), with the linear formula TiCl4 · 2THF and a molecular weight of 333.89 g/mol, is a Lewis acid and synthetic reagent. This compound serves as a valuable intermediate in various chemical syntheses, particularly where controlled delivery of titanium tetrachloride is required. It is typically supplied with an assay of 97% and requires storage at 2-8°C due to its reactivity.

IUPAC
Tetrachlorobis(tetrahydrofuran)titanium
Synonyms
Tetrachlorobis(tetrahydrofuran)titanium
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Titanium(IV) chloride tetrahydrofuran complex (TiCl4 · 2THF) — chemical structure, CAS 31011-57-1; Chemistry, fine chemical supplied by Tech Serve Solutions
AcidsAcids & BasesChemical SynthesisLewis AcidsSynthetic ReagentsTitanium More...
01 /Applications

Lewis Acid Catalysis

As a potent Lewis acid, this complex can catalyse a range of organic transformations, including Diels-Alder reactions and Friedel-Crafts alkylations. Its solubility in organic solvents like THF offers advantages in homogeneous catalysis.

Precursor in Materials Science

It can be employed as a precursor for the deposition of titanium-containing thin films or nanoparticles. The controlled release of TiCl4 from the THF complex allows for specific processing conditions.

Reagent in Organic Synthesis

The complex acts as a source of titanium for various synthetic applications, offering a more manageable alternative to anhydrous titanium(IV) chloride. It is used in the preparation of organometallic compounds and other titanium derivatives.

02 /Properties
Molecular weight333.89
Linear formulaTiCl4 · 2THF
Assay97%
Storage temperature2-8°C
Melting point126-128 °C(lit.)
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
Danger

Hazard statements

  • H228Flammable solid
  • H314Causes severe skin burns and eye damage

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P280Wear protective gloves, clothing and eye/face protection
  • P305IF IN EYES
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentEyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Flash point-17 °C / 1.4 °F
Transport (UN / ADR)UN 2925 4.1/PG 2
Water hazard class (WGK, DE)3
Hazard codes (EU)C
Risk statements (R)14-34-37
Safety statements (S)26-36/37/39-45
Supplemental hazardsReacts violently with water.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
31011-57-1
MDL number
MFCD00077884
PubChem substance
24864161
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Titanium(IV) chloride tetrahydrofuran complex used for?

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Titanium(IV) chloride tetrahydrofuran complex is used as a Lewis acid catalyst, a precursor in materials science for titanium-containing thin films, and a reagent in organic synthesis for introducing titanium into molecules.

What is the CAS number and formula for this compound?

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The CAS number is 31011-57-1 and the linear formula is TiCl4 · 2THF.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Titanium(IV) chloride tetrahydrofuran complex with an assay of 97%. This product is not represented as USP, BP, EP, or any other pharmacopoeia grade.

What are the primary safety concerns when handling this chemical?

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This compound is highly reactive and classified as Danger. It is flammable (flash point -17°C) and corrosive, causing severe skin burns and eye damage. It reacts violently with water. Appropriate personal protective equipment, including eyeshields, gloves, and a suitable respirator, must be used. Handle only under inert atmosphere and avoid contact with water.

How is Titanium(IV) chloride tetrahydrofuran complex packed, shipped, and exported?

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Tech Serve Solutions professionally packs, ships, and exports chemicals globally, adhering to all relevant transport regulations for hazardous materials like UN 2925.

How can I request a quote or sample?

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To request a quote or sample of Titanium(IV) chloride tetrahydrofuran complex, please contact our sales department via the website or by telephone.

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