Tech Serve Solutions

Hydrofluoric acid

CAS 7664-39-3HFAcids & Bases

Hydrofluoric acid (HF), CAS 7664-39-3, is a highly corrosive and versatile inorganic acid with a molecular weight of 20.01 g/mol. It exists as a clear, colourless liquid and is a vital reagent in numerous industrial and laboratory processes. Its unique ability to dissolve glass and its reactivity make it indispensable for etching, cleaning, and in the production of various fluorinated compounds.

IUPAC
HF
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Hydrofluoric acid (HF) — chemical structure, CAS 7664-39-3; Chemistry, fine chemical supplied by Tech Serve Solutions
AcidsAcids & BasesChemical SynthesisInorganic AcidsSynthetic Reagents
01 /Applications

Glass Etching and Frosting

Hydrofluoric acid is widely used to etch intricate designs into glass surfaces or to create a frosted appearance. Its chemical reaction with silicon dioxide (SiO2) in glass allows for precise material removal.

Semiconductor Manufacturing

In the microelectronics industry, HF is critical for cleaning and etching silicon wafers. It selectively removes native oxides and contaminants, ensuring the integrity of semiconductor devices.

Chemical Synthesis

As a key inorganic acid, hydrofluoric acid serves as a fluorinating agent and catalyst in the synthesis of a wide array of organic and inorganic fluorochemicals, including refrigerants and polymers.

Metal Pickling and Cleaning

It is employed in metal treatment processes, such as pickling stainless steel, to remove surface oxides and scale. Its effectiveness extends to cleaning and preparing metal surfaces for further processing.

Petroleum Refining

Hydrofluoric acid acts as a catalyst in alkylation units within petroleum refineries. This process is essential for producing high-octane gasoline components.

02 /Properties
Molecular weight20.01
Empirical formulaHF
Assay48%48.0-51.0% (ACS specification)
Density1.15 g/mL at 25 °C(lit.)
Concentration≥40%
Vapour pressure25 mmHg (20 °C)
Vapour density1.27 (vs air)
Impurities tested≤0.01% fluorosilicic acid
03 /Safety & handling
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Toxic (GHS06)
Toxic
Danger

Hazard statements

  • H300Fatal if swallowed
  • H310Fatal in contact with skin
  • H314Causes severe skin burns and eye damage
  • H330Fatal if inhaled

Precautionary statements

  • P260Do not breathe dust, fume, gas, mist, vapours or spray
  • P264Wash thoroughly after handling
  • P280Wear protective gloves, clothing and eye/face protection
  • P284Wear respiratory protection
  • P301IF SWALLOWED
  • P302IF ON SKIN
Protective equipmentEyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges
Transport (UN / ADR)UN 1790 8/PG 2
Water hazard class (WGK, DE)2
Hazard codes (EU)T+,C
Risk statements (R)26/27/28-35
Safety statements (S)7/9-26-36/37-45
Cation tracesAs: ≤0.005 ppmCu: ≤0.1 ppmFe: ≤1 ppmheavy metals (as Pb): ≤0.5 ppm
Anion tracesSO42- and SO32-: ≤5 ppmchloride (Cl-): ≤5 ppmphosphate (PO43-): ≤1 ppm
Ignition residue≤5 ppm

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
7664-39-3
MDL number
MFCD00011346
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is Hydrofluoric acid used for?

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Hydrofluoric acid is used for glass etching, semiconductor manufacturing, chemical synthesis, metal pickling and cleaning, and as a catalyst in petroleum refining.

What are the CAS number and formula for Hydrofluoric acid?

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The CAS number for Hydrofluoric acid is 7664-39-3 and its chemical formula is HF.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Hydrofluoric acid with an assay of 48.0-51.0% (ACS specification). We do not represent this product as USP, BP, or EP grade.

What are the main safety hazards associated with Hydrofluoric acid?

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Hydrofluoric acid is extremely corrosive and toxic. Hazards include severe burns on contact, fatal ingestion, inhalation, and skin absorption. Appropriate personal protective equipment, including eyeshields, face shields, and chemical-resistant gloves and respirators, is mandatory.

How is Hydrofluoric acid packed and exported?

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Hydrofluoric acid is packed and shipped in accordance with UN 1790 regulations for hazardous materials, typically in specialised containers suitable for corrosive liquids, ensuring safe handling during export.

How can I request a quote or sample for Hydrofluoric acid?

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Please contact our sales team via the website or your dedicated account manager to request a quotation or to arrange for a product sample.

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