Boron trifluoride-methanol solution
Boron trifluoride-methanol solution (CAS 373-57-9), with the linear formula BF₃·MeOH and a molecular weight of 99.85 g/mol, is a chemical reagent supplied by TSS. This 14% solution in methanol is primarily utilised as a Lewis acid catalyst in organic synthesis, particularly in esterification and polymerisation reactions. Its reactive nature necessitates careful handling and storage.

Esterification Catalyst
Boron trifluoride-methanol solution serves as an effective catalyst for the esterification of carboxylic acids with alcohols. It facilitates rapid formation of esters under mild conditions.
Polymerisation Initiator
This reagent can act as an initiator or catalyst in certain polymerisation processes. Its Lewis acidic properties enable the activation of monomers for chain growth.
Organic Synthesis Reagent
Utilised broadly in organic synthesis, it participates in various reactions requiring a strong Lewis acid, such as Friedel-Crafts alkylations and acylations, and as a source of the BF₃ moiety.
| Molecular weight | 99.85 |
|---|---|
| Linear formula | BF3 · MeOH |
| Boiling point | 59 °C/4 mmHg |
| Density | 1.203 g/mL at 25 °C |
| Concentration | 14% in methanol |
| Vapour pressure | 19.5 mmHg (20 °C) |
| Autoignition temp | 788 °F |
| Storage temperature | 2-8°C |




Hazard statements
- H225Highly flammable liquid and vapour
- H301Toxic if swallowed
- H311Toxic in contact with skin
- H314Causes severe skin burns and eye damage
- H331Toxic if inhaled
- H370Causes damage to organs
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P260Do not breathe dust, fume, gas, mist, vapours or spray
- P280Wear protective gloves, clothing and eye/face protection
- P301IF SWALLOWED
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 16 °C / 60.8 °F |
| Transport (UN / ADR) | UN 3286 3/PG 2 |
| Water hazard class (WGK, DE) | 1 |
| Hazard codes (EU) | F,T+ |
| Risk statements (R) | 11-14-24/25-26-35-39/23/24/25 |
| Safety statements (S) | 16-26-28-36/37/39-45 |
| Supplemental hazards | Reacts violently with water. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Boron trifluoride-methanol solution used for?
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Boron trifluoride-methanol solution is primarily used as a Lewis acid catalyst in organic synthesis, particularly for esterification and polymerisation reactions. It is also a valuable reagent for introducing the BF₃ group in various chemical transformations.
What are the CAS number and formula for Boron trifluoride-methanol solution?
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The CAS number is 373-57-9 and the linear formula is BF₃·MeOH.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Boron trifluoride-methanol solution at a concentration of 14% in methanol. This product is supplied for laboratory and research purposes, and TSS does not represent it as meeting USP, BP, or EP pharmacopoeia standards.
How should Boron trifluoride-methanol solution be handled?
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Boron trifluoride-methanol solution is a Danger material requiring strict safety precautions. It is highly flammable, corrosive, and toxic. Handling requires appropriate personal protective equipment, including gloves, eye protection (goggles and face shield), and respiratory protection. It reacts violently with water. Storage should be in a cool, well-ventilated area, away from incompatible materials, and at 2-8°C.
How is Boron trifluoride-methanol solution packed and shipped?
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Boron trifluoride-methanol solution is packed and shipped in compliance with all relevant regulations for hazardous materials. As a specialist global supplier, TSS ensures proper packaging and documentation for international export.
How can I request a sample or quote for Boron trifluoride-methanol solution?
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To request a sample or quote, please contact the TSS sales team via the website or listed contact details, specifying the product name and CAS number.
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