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2-Butenylmagnesium chloride solution

CAS 22649-70-3CH3CH=CHCH2MgClChemical Synthesis

2-Butenylmagnesium chloride solution (CAS 22649-70-3), with the linear formula CH3CH=CHCH2MgCl and a molecular weight of 114.86 g/mol, is a vital organometallic reagent. Supplied as a 0.5 M solution in Tetrahydrofuran (THF), it serves as a potent nucleophile in organic synthesis. This compound is primarily employed in the formation of carbon-carbon bonds, facilitating the construction of more complex molecular architectures in research and development.

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2-Butenylmagnesium chloride solution (CH3CH=CHCH2MgCl) — chemical structure, CAS 22649-70-3; Chemistry, fine chemical supplied by Tech Serve Solutions
AlkylChemical SynthesisGrignard ReagentsOrganometallic Reagents
01 /Applications

Carbon-Carbon Bond Formation

As a Grignard reagent, 2-Butenylmagnesium chloride solution is instrumental in nucleophilic addition reactions. It efficiently adds to electrophilic carbon centers such as aldehydes, ketones, esters, and epoxides, enabling the synthesis of substituted alkenes and alcohols.

Organometallic Synthesis

This compound is a key building block in organometallic chemistry. Its utility lies in introducing the 2-butenyl group into organic molecules, a common motif in natural products and pharmaceuticals.

Research and Development

Utilised extensively in academic and industrial research laboratories for the development of novel synthetic methodologies and the exploration of new chemical entities. Its predictable reactivity makes it a reliable tool for synthetic chemists.

02 /Properties
Molecular weight114.86
Linear formulaCH3CH=CHCH2MgCl
Density0.921 g/mL at 25 °C
Concentration0.5 M in THF
03 /Safety & handling
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Toxic (GHS06)
Toxic
GHS hazard pictogram: Health hazard (GHS08)
Health hazard
Danger

Hazard statements

  • H302Harmful if swallowed
  • H314Causes severe skin burns and eye damage
  • H330Fatal if inhaled
  • H335May cause respiratory irritation
  • H351Suspected of causing cancer

Precautionary statements

  • P260Do not breathe dust, fume, gas, mist, vapours or spray
  • P280Wear protective gloves, clothing and eye/face protection
  • P284Wear respiratory protection
  • P305IF IN EYES
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Transport (UN / ADR)UN 2924 8(3) / PGII
Water hazard class (WGK, DE)3
Hazard codes (EU)F,C
Risk statements (R)14/15-19-20/21/22-34-37-40
Safety statements (S)26-36/37/39-43-45
Supplemental hazardsMay form explosive peroxides.

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
22649-70-3
MDL number
MFCD01321226
PubChem substance
24866262
05 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

06 /Frequently asked questions

What is 2-Butenylmagnesium chloride solution used for?

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2-Butenylmagnesium chloride solution is primarily used for carbon-carbon bond formation through nucleophilic addition reactions in organic synthesis and organometallic chemistry research.

What is the CAS number and chemical formula for 2-Butenylmagnesium chloride solution?

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The CAS number is 22649-70-3, and the linear chemical formula is CH3CH=CHCH2MgCl.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies 2-Butenylmagnesium chloride solution at a concentration of 0.5 M in THF. This product is intended for laboratory and research use; TSS does not represent it as USP, BP, EP, or other pharmacopoeial grades.

How should 2-Butenylmagnesium chloride solution be handled safely?

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Handling requires extreme caution due to its corrosive nature, toxicity upon inhalation and ingestion/skin contact, and potential to form explosive peroxides. Always use appropriate personal protective equipment, including a full-face respirator, gloves, goggles, and protective clothing, in a well-ventilated area, away from ignition sources and incompatible materials. Refer to the Safety Data Sheet for detailed guidance.

How is 2-Butenylmagnesium chloride solution packed, shipped, and exported?

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This product is classified under UN 2924, UN Hazard Class 8 (Corrosive) with subsidiary risk 3 (Flammable), Packing Group II. It is packed and shipped according to strict international regulations for hazardous materials, suitable for global export.

How can I request a quote or sample for 2-Butenylmagnesium chloride solution?

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To request a quote or sample, please use the contact form on our website or email our sales department directly, providing your details and the product CAS number 22649-70-3.

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