Titanium(IV) chloride tetrahydrofuran complex
Titanium(IV) chloride tetrahydrofuran complex (CAS 31011-57-1), with the linear formula TiCl4 · 2THF and a molecular weight of 333.89 g/mol, is a Lewis acid and synthetic reagent. This compound serves as a valuable intermediate in various chemical syntheses, particularly where controlled delivery of titanium tetrachloride is required. It is typically supplied with an assay of 97% and requires storage at 2-8°C due to its reactivity.
- IUPAC
- Tetrachlorobis(tetrahydrofuran)titanium
- Synonyms
- Tetrachlorobis(tetrahydrofuran)titanium

Lewis Acid Catalysis
As a potent Lewis acid, this complex can catalyse a range of organic transformations, including Diels-Alder reactions and Friedel-Crafts alkylations. Its solubility in organic solvents like THF offers advantages in homogeneous catalysis.
Precursor in Materials Science
It can be employed as a precursor for the deposition of titanium-containing thin films or nanoparticles. The controlled release of TiCl4 from the THF complex allows for specific processing conditions.
Reagent in Organic Synthesis
The complex acts as a source of titanium for various synthetic applications, offering a more manageable alternative to anhydrous titanium(IV) chloride. It is used in the preparation of organometallic compounds and other titanium derivatives.
| Molecular weight | 333.89 |
|---|---|
| Linear formula | TiCl4 · 2THF |
| Assay | 97% |
| Storage temperature | 2-8°C |
| Melting point | 126-128 °C(lit.) |


Hazard statements
- H228Flammable solid
- H314Causes severe skin burns and eye damage
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Flash point | -17 °C / 1.4 °F |
| Transport (UN / ADR) | UN 2925 4.1/PG 2 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | C |
| Risk statements (R) | 14-34-37 |
| Safety statements (S) | 26-36/37/39-45 |
| Supplemental hazards | Reacts violently with water. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Titanium(IV) chloride tetrahydrofuran complex used for?
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Titanium(IV) chloride tetrahydrofuran complex is used as a Lewis acid catalyst, a precursor in materials science for titanium-containing thin films, and a reagent in organic synthesis for introducing titanium into molecules.
What is the CAS number and formula for this compound?
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The CAS number is 31011-57-1 and the linear formula is TiCl4 · 2THF.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Titanium(IV) chloride tetrahydrofuran complex with an assay of 97%. This product is not represented as USP, BP, EP, or any other pharmacopoeia grade.
What are the primary safety concerns when handling this chemical?
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This compound is highly reactive and classified as Danger. It is flammable (flash point -17°C) and corrosive, causing severe skin burns and eye damage. It reacts violently with water. Appropriate personal protective equipment, including eyeshields, gloves, and a suitable respirator, must be used. Handle only under inert atmosphere and avoid contact with water.
How is Titanium(IV) chloride tetrahydrofuran complex packed, shipped, and exported?
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Tech Serve Solutions professionally packs, ships, and exports chemicals globally, adhering to all relevant transport regulations for hazardous materials like UN 2925.
How can I request a quote or sample?
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To request a quote or sample of Titanium(IV) chloride tetrahydrofuran complex, please contact our sales department via the website or by telephone.
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