Titanium(III) chloride tetrahydrofuran complex (1:3)
Titanium(III) chloride tetrahydrofuran complex (1:3) (CAS: 18039-90-2), with the empirical formula C12H24Cl3O3Ti and a molecular weight of 370.54 g/mol, is a valuable organometallic compound. It is primarily utilised as a catalyst and reagent in various chemical synthesis processes, particularly in polymerisation reactions and organic transformations. Its tetrahydrofuran coordination enhances solubility and reactivity compared to anhydrous titanium(III) chloride.
- IUPAC
- THF-titanium trichloride complex, (3:1),Titanium trichloride tetrahydrofuran complex (1:3),Titanium trichloride tri(THF),Titanium trichloride tris(tetrahydrofuran),Trichlorotris(THF)titanium,Trichlorotris(tetrahydrofuran)titanium
- Synonyms
- THF-titanium trichloride complex, (3:1)Titanium trichloride tetrahydrofuran complex (1:3)Titanium trichloride tri(THF)Titanium trichloride tris(tetrahydrofuran)Trichlorotris(THF)titaniumTrichlorotris(tetrahydrofuran)titanium

Catalysis in Organic Synthesis
This titanium complex serves as an effective catalyst in various organic transformations. Its ability to participate in redox reactions and coordinate with substrates makes it useful for promoting reactions like cyclopropanations and reductive couplings.
Polymerisation Initiator
The compound can act as an initiator or co-catalyst in certain polymerisation processes. It is particularly relevant in the synthesis of specific polymers where control over molecular weight and microstructure is desired.
Precursor for Materials Science
As a source of titanium, this complex can be employed in the preparation of advanced materials and thin films. Its controlled decomposition or reaction can lead to titanium-containing oxides or other inorganic structures.
| Molecular weight | 370.54 |
|---|---|
| Empirical formula | C12H24Cl3O3Ti |
| Assay | 97% |
| Storage temperature | 2-8°C |
| Melting point | >250 °C(lit.) |


Hazard statements
- H228Flammable solid
- H314Causes severe skin burns and eye damage
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 2925 4.1/PG 2 |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,C |
| Risk statements (R) | 11-34 |
| Safety statements (S) | 16-26-36/37/39-45 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Titanium(III) chloride tetrahydrofuran complex (1:3) used for?
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Titanium(III) chloride tetrahydrofuran complex (1:3) is primarily used as a catalyst and reagent in organic synthesis, particularly for polymerisation reactions and other chemical transformations.
What is the CAS number and formula for Titanium(III) chloride tetrahydrofuran complex (1:3)?
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The CAS number is 18039-90-2, and the empirical formula is C12H24Cl3O3Ti.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Titanium(III) chloride tetrahydrofuran complex (1:3) at a purity of 97%. This product is not represented as USP, BP, EP, or any other pharmacopoeia grade.
How should Titanium(III) chloride tetrahydrofuran complex (1:3) be handled safely?
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This compound is classified as Danger, with hazards including flammability (H228) and severe skin burns and eye damage (H314). It requires stringent safety precautions, including appropriate personal protective equipment such as eyeshields, faceshields, gloves, and suitable respiratory protection.
How is this chemical shipped and exported?
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Titanium(III) chloride tetrahydrofuran complex (1:3) is shipped and exported under UN 2925, hazard class 4.1, packing group II. Storage is recommended at 2-8°C.
How can I request a sample or quote?
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To request a sample or a quote for Titanium(III) chloride tetrahydrofuran complex (1:3), please contact the Tech Serve Solutions sales team through our website or by phone.
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