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Methyl formate

CAS 107-31-3HCO2CH3Organic Building Blocks

Methyl formate (CAS: 107-31-3, HCO2CH3) is a volatile, flammable ester with a molar mass of 60.05 g/mol. It is a clear, colourless liquid that serves as a fundamental building block in organic synthesis. Its applications span various chemical processes, notably as a source of the formyl group and in the production of formic acid and formamide. It is also used as a solvent and as a refrigerant.

IUPAC
Formic acid methyl ester
Synonyms
Formic acid methyl esterMethyl ester of formic acid
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Methyl formate (HCO2CH3) — chemical structure, CAS 107-31-3; Chemistry, fine chemical supplied by Tech Serve Solutions
Building BlocksC2 to C5Carbonyl CompoundsChemical SynthesisEsters
01 /Applications

Chemical Synthesis

Methyl formate is widely employed as a key intermediate and building block in organic synthesis. It is a primary reagent for introducing the formyl group into organic molecules, enabling the construction of more complex compounds.

Solvent Applications

Due to its solvent properties, methyl formate is utilised in various industrial applications. It can be found in formulations for specialised cleaning agents and as a solvent in certain chemical reactions where its volatility and solvency are advantageous.

Refrigerant

Historically and in specific niche applications, methyl formate has been used as a refrigerant. Its thermodynamic properties allow it to function as a working fluid in refrigeration cycles, though its flammability requires careful handling.

Precursor for Other Chemicals

It serves as a precursor for the synthesis of other essential chemicals, including formic acid and formamide. These downstream products have broad industrial relevance in textiles, agriculture, and pharmaceuticals.

02 /Properties
Molecular weight60.05
Linear formulaHCO2CH3
Assay≥98.5% (GC)
Gradeabsolutepuriss.
Boiling point32-34 °C(lit.)
Density0.974 g/mL at 20 °C(lit.)
Refractive indexn20/D 1.343(lit.)n20/D 1.344
Melting point−100 °C(lit.)
Vapour density2.1 (vs air)
Autoignition temp842 °F
Impurities tested≤0.01% water
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Harmful / irritant (GHS07)
Harmful / irritant
Danger

Hazard statements

  • H224Extremely flammable liquid and vapour
  • H302Harmful if swallowed
  • H319Causes serious eye irritation
  • H335May cause respiratory irritation

Precautionary statements

  • P210Keep away from heat, sparks and open flames. No smoking
  • P261Avoid breathing dust, fume, gas or vapours
  • P305IF IN EYES
Protective equipmentEyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
Flash point-19 °C / -2.2 °F
Transport (UN / ADR)UN 1243 3 / PGI
Water hazard class (WGK, DE)1
Hazard codes (EU)F+,Xn
Risk statements (R)12-20/22-36/37
Safety statements (S)9-16-24-26-33

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
107-31-3
MDL number
MFCD00003291
Beilstein registry
1734623
05 /Additional specifications
Expl Lim23 %
Evapn Residue≤0.0005%
Shelf Life(limited shelf life, expiry date on the label)
06 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

07 /Frequently asked questions

What is Methyl formate used for?

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Methyl formate is used as a building block in chemical synthesis, a solvent, a refrigerant, and a precursor for formic acid and formamide production.

What are the CAS number and formula for Methyl formate?

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The CAS number for Methyl formate is 107-31-3, and its chemical formula is HCO2CH3.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Methyl formate with a purity of ≥98.5% (GC), in absolute puriss. grade. TSS does not represent this product as USP, BP, or EP grade.

What are the key safety considerations when handling Methyl formate?

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Methyl formate is extremely flammable (H224) and presents health hazards including being harmful if swallowed or inhaled (H302, H332) and causing serious eye irritation and respiratory irritation (H319, H335). Always handle with appropriate personal protective equipment in a well-ventilated area.

How is Methyl formate typically packed, shipped, and exported?

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Methyl formate is supplied in various container sizes suitable for laboratory and industrial use. Tech Serve Solutions expertly handles the export of this chemical worldwide, adhering to all international shipping regulations for hazardous materials.

How can I request a sample or quote for Methyl formate?

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To request a sample or a quote for Methyl formate, please contact our sales team through the website or provide your details via the online enquiry form.

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