Methyl formate
Methyl formate (CAS: 107-31-3, HCO2CH3) is a volatile, flammable ester with a molar mass of 60.05 g/mol. It is a clear, colourless liquid that serves as a fundamental building block in organic synthesis. Its applications span various chemical processes, notably as a source of the formyl group and in the production of formic acid and formamide. It is also used as a solvent and as a refrigerant.
- IUPAC
- Formic acid methyl ester
- Synonyms
- Formic acid methyl esterMethyl ester of formic acid

Chemical Synthesis
Methyl formate is widely employed as a key intermediate and building block in organic synthesis. It is a primary reagent for introducing the formyl group into organic molecules, enabling the construction of more complex compounds.
Solvent Applications
Due to its solvent properties, methyl formate is utilised in various industrial applications. It can be found in formulations for specialised cleaning agents and as a solvent in certain chemical reactions where its volatility and solvency are advantageous.
Refrigerant
Historically and in specific niche applications, methyl formate has been used as a refrigerant. Its thermodynamic properties allow it to function as a working fluid in refrigeration cycles, though its flammability requires careful handling.
Precursor for Other Chemicals
It serves as a precursor for the synthesis of other essential chemicals, including formic acid and formamide. These downstream products have broad industrial relevance in textiles, agriculture, and pharmaceuticals.
| Molecular weight | 60.05 |
|---|---|
| Linear formula | HCO2CH3 |
| Assay | ≥98.5% (GC) |
| Grade | absolutepuriss. |
| Boiling point | 32-34 °C(lit.) |
| Density | 0.974 g/mL at 20 °C(lit.) |
| Refractive index | n20/D 1.343(lit.)n20/D 1.344 |
| Melting point | −100 °C(lit.) |
| Vapour density | 2.1 (vs air) |
| Autoignition temp | 842 °F |
| Impurities tested | ≤0.01% water |


Hazard statements
- H224Extremely flammable liquid and vapour
- H302Harmful if swallowed
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US) |
|---|---|
| Flash point | -19 °C / -2.2 °F |
| Transport (UN / ADR) | UN 1243 3 / PGI |
| Water hazard class (WGK, DE) | 1 |
| Hazard codes (EU) | F+,Xn |
| Risk statements (R) | 12-20/22-36/37 |
| Safety statements (S) | 9-16-24-26-33 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Expl Lim | 23 % |
|---|---|
| Evapn Residue | ≤0.0005% |
| Shelf Life | (limited shelf life, expiry date on the label) |
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Methyl formate used for?
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Methyl formate is used as a building block in chemical synthesis, a solvent, a refrigerant, and a precursor for formic acid and formamide production.
What are the CAS number and formula for Methyl formate?
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The CAS number for Methyl formate is 107-31-3, and its chemical formula is HCO2CH3.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Methyl formate with a purity of ≥98.5% (GC), in absolute puriss. grade. TSS does not represent this product as USP, BP, or EP grade.
What are the key safety considerations when handling Methyl formate?
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Methyl formate is extremely flammable (H224) and presents health hazards including being harmful if swallowed or inhaled (H302, H332) and causing serious eye irritation and respiratory irritation (H319, H335). Always handle with appropriate personal protective equipment in a well-ventilated area.
How is Methyl formate typically packed, shipped, and exported?
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Methyl formate is supplied in various container sizes suitable for laboratory and industrial use. Tech Serve Solutions expertly handles the export of this chemical worldwide, adhering to all international shipping regulations for hazardous materials.
How can I request a sample or quote for Methyl formate?
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To request a sample or a quote for Methyl formate, please contact our sales team through the website or provide your details via the online enquiry form.
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