Methyl 1-cyclohexene-1-carboxylate
Methyl 1-cyclohexene-1-carboxylate (CAS: 18448-47-0; Formula: C6H9CO2CH3; MW: 140.18) is a versatile organic ester. It serves as a valuable building block in chemical synthesis, particularly in the construction of complex cyclic structures. Its applications include diastereoselective synthesis and the creation of novel dibenzo[b,d]furan and benzo[b]phenaleno[2,1-d]furan derivatives. Available from Tech Serve Solutions with a purity of ≥97%.
Diastereoselective Synthesis
Methyl 1-cyclohexene-1-carboxylate has been utilised in the diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols, showcasing its utility in stereospecific organic transformations.
Synthesis of Dibenzo[b,d]furan Derivatives
This compound is employed in the synthesis of complex polycyclic molecules, specifically methyl 7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate.
Synthesis of Benzo[b]phenaleno[2,1-d]furan Derivatives
It is also a precursor in the synthesis of ethyl 7-oxo-7b,8,9,10,11,11a-hexahydro-7H-benzo[b]phenaleno[2,1-d]furan-11a-carboxylate, contributing to the development of fused ring systems.
| Molecular weight | 140.18 |
|---|---|
| Linear formula | C6H9CO2CH3 |
| Assay | ≥97% |
| Boiling point | 190-192 °C58-60 °C/0.1 mmHg(lit.) |
| Density | 1.028 g/mL at 20 °C(lit.) |
| Application | Methyl 1-cyclohexene-1-carboxylate was used in:• diastereoselective synthesis of cis-1,2-dialkenylcyclopropanols1• synthesis of methyl 7,7-dimethyl-9-oxo-1,3,4,4a,6,7,8,9,9b-decahydrodibenzo[b,d]furan-4a-carboxylate2• synthesis of ethyl 7-oxo-7b,8,9,10,11,11a-hexahydro-7H-benzo[b]phenaleno[2,1-d]furan-11a-carboxylate2 |
| Protective equipment | Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 71 °C / 159.8 °F |
| Transport (UN / ADR) | NA 1993 / PGIII |
| Water hazard class (WGK, DE) | 3 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Methyl 1-cyclohexene-1-carboxylate used for?
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Methyl 1-cyclohexene-1-carboxylate is used as a building block in chemical synthesis, notably for creating complex cyclic compounds such as cis-1,2-dialkenylcyclopropanols and various dibenzo[b,d]furan and benzo[b]phenaleno[2,1-d]furan derivatives.
What are the CAS number and chemical formula for Methyl 1-cyclohexene-1-carboxylate?
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The CAS number is 18448-47-0, and the chemical formula is C6H9CO2CH3.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Methyl 1-cyclohexene-1-carboxylate with a purity of ≥97%. This is a technical grade suitable for research and synthesis; TSS does not represent it as USP, BP, EP, or pharmacopoeia grade.
How should Methyl 1-cyclohexene-1-carboxylate be handled safely?
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Handle with care using appropriate personal protective equipment, including eyeshields, chemical-resistant gloves, and respiratory protection (e.g., type ABEK respirator filter). Ensure adequate ventilation. Refer to the Safety Data Sheet for full details, noting it has a flash point of 71 °C (159.8 °F) and is classified under WGK Germany 3.
How is Methyl 1-cyclohexene-1-carboxylate shipped and exported?
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Methyl 1-cyclohexene-1-carboxylate is classified as NA 1993 / PGIII for transport. Tech Serve Solutions is an experienced global supplier and exporter, adhering to all shipping regulations.
How can I request a sample or quote for Methyl 1-cyclohexene-1-carboxylate?
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To request a sample or a quote, please contact the Tech Serve Solutions sales team through our website or by phone, providing your specific requirements.
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