Methacryloyl chloride
Methacryloyl chloride (CAS: 920-46-7) is a highly reactive acyl chloride and a key building block in organic synthesis. Its molecular formula is CH2=C(CH3)COCl, with a molecular weight of 104.53 g/mol. This compound serves as a vital intermediate for introducing the methacryloyl functional group into various molecules, finding significant utility in polymer science and materials research. It is a corrosive and flammable liquid requiring careful handling.

Monomer Synthesis
Methacryloyl chloride is a crucial precursor for synthesising methacrylate monomers. These monomers are widely used in the production of polymers and copolymers for applications such as coatings, adhesives, and dental materials.
Organic Synthesis Intermediate
As a reactive acyl halide, it participates in numerous acylation reactions, enabling the formation of esters, amides, and other derivatives. This makes it a valuable building block in the synthesis of complex organic molecules, including pharmaceuticals and agrochemicals.
Polymer Modification
It can be employed to modify existing polymers, introducing methacryloyl groups that can subsequently be cross-linked or functionalised. This allows for tailoring polymer properties for specific material science applications.
| Molecular weight | 104.53 |
|---|---|
| Linear formula | CH2=C(CH3)COCl |
| Assay | ≥97.0% (GC) |
| Grade | purum |
| Boiling point | 95-96 °C(lit.) |
| Density | 1.08 g/mL at 20 °C1.07 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.442(lit.)n20/D 1.444 |
| Storage temperature | 2-8°C |
| Contains / stabiliser | ~0.02% 2,6-di-tert-butyl-4-methylphenol as stabilizer |
| Impurities tested | ≤1000 mg/kg total sulfur (as SO4) |



Hazard statements
- H225Highly flammable liquid and vapour
- H302Harmful if swallowed
- H314Causes severe skin burns and eye damage
- H317May cause an allergic skin reaction
- H330Fatal if inhaled
- H412Harmful to aquatic life with long-lasting effects
Precautionary statements
- P210Keep away from heat, sparks and open flames. No smoking
- P260Do not breathe dust, fume, gas, mist, vapours or spray
- P273Avoid release to the environment
- P280Wear protective gloves, clothing and eye/face protection
- P284Wear respiratory protection
- P305IF IN EYES
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 12 °C / 53.6 °F |
| Transport (UN / ADR) | UN 3383 6.1/PG 1 |
| Water hazard class (WGK, DE) | 2 |
| Hazard codes (EU) | F,T+ |
| Risk statements (R) | 11-22-26-34-43-52/53 |
| Safety statements (S) | 16-26-28-29-33-36/37/39-45 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Quality | dist. |
|---|
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Methacryloyl chloride used for?
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Methacryloyl chloride (CAS: 920-46-7) is used as a reactive intermediate in organic synthesis, particularly for introducing the methacryloyl group, and in the production of methacrylate monomers for polymers and materials science applications.
What is the CAS number and formula for Methacryloyl chloride?
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The CAS number for Methacryloyl chloride is 920-46-7, and its linear formula is CH2=C(CH3)COCl.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Methacryloyl chloride with a purity of ≥97.0% (GC), grade purum, quality distilled. We do not represent this product as USP, BP, or EP grade.
How should Methacryloyl chloride be handled safely?
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Methacryloyl chloride is a dangerous substance (GHS02, GHS05, GHS06, Danger). It is highly flammable (H225), harmful if swallowed (H302), causes severe skin burns and eye damage (H314), may cause an allergic skin reaction (H317), and is fatal if inhaled (H330). It also has long-lasting harmful effects on aquatic life (H412). Handle with appropriate personal protective equipment including gloves, eye protection, and respiratory protection in a well-ventilated area. Refer to the safety data sheet for detailed guidance.
How is Methacryloyl chloride packed and shipped?
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Methacryloyl chloride is shipped as UN 3383, Hazard Class 6.1 (Toxic substances), Packing Group I. Specific packaging details are available upon request, and TSS complies with all relevant export regulations.
How can I request a sample or quote for Methacryloyl chloride?
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To request a sample or a quote for Methacryloyl chloride, please contact our sales team via the website or by phone. Please specify the quantity required and your delivery location.
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