Lithium diisobutyl-tert-butoxyaluminum hydride solution
Lithium diisobutyl-tert-butoxyaluminum hydride solution (CAS 77299-63-9) is a powerful reducing agent supplied by Tech Serve Solutions. With a molecular weight of 222.27 g/mol, this organoaluminum compound is formulated as a 0.25 M solution in THF/hexanes. It is primarily utilized in organic synthesis for selective reductions, offering a versatile tool for chemists in research and development.
- IUPAC
- LDBBA

Selective Reduction Reactions
This organoaluminum hydride is employed in various reduction reactions within organic synthesis. It can selectively reduce functional groups under controlled conditions, making it valuable for multi-step synthetic pathways.
Organometallic Synthesis
As an organometallic reagent, it plays a role in the synthesis of complex organic molecules. Its reactivity profile allows for specific transformations essential in the development of new chemical entities.
Chemical Research and Development
Used in academic and industrial R&D settings, this compound aids in exploring novel synthetic routes and developing new materials. Its availability as a solution simplifies handling and precise dosing in laboratory environments.
| Molecular weight | 222.27 |
|---|---|
| Empirical formula | C12H28AlLiO |
| Density | 0.795 g/mL at 25 °C |
| Concentration | 0.25 M in THF/hexanes |
| Storage temperature | 2-8°C |




Hazard statements
- H261In contact with water releases flammable gas
- H304May be fatal if swallowed and enters airways
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
- H336May cause drowsiness or dizziness
- H361F
- H373May cause damage to organs through prolonged exposure
- H411Toxic to aquatic life with long-lasting effects
Precautionary statements
- P231Handle under inert gas
- P261Avoid breathing dust, fume, gas or vapours
- P273Avoid release to the environment
- P281Use personal protective equipment as required
- P301IF SWALLOWED
- P422
| Transport (UN / ADR) | UN 3399 4.3/PG 2 |
|---|---|
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | F,Xn,N |
| Risk statements (R) | 15-19-36/37/38-48/20-51/53-62-65-67 |
| Safety statements (S) | 26-36/37-43-61-62 |
| Supplemental hazards | May form explosive peroxides. |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Lithium diisobutyl-tert-butoxyaluminum hydride solution used for?
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Lithium diisobutyl-tert-butoxyaluminum hydride solution (CAS 77299-63-9) is primarily used as a selective reducing agent in organic synthesis and in the broader field of chemical research and development.
What is the CAS number and formula for this compound?
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The CAS number is 77299-63-9 and the empirical formula (Hill notation) is C12H28AlLiO.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Lithium diisobutyl-tert-butoxyaluminum hydride solution at a concentration of 0.25 M in THF/hexanes. TSS does not represent this product as USP, BP, or EP grade.
How should Lithium diisobutyl-tert-butoxyaluminum hydride solution be handled and stored?
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This compound is highly reactive and flammable. It should be handled under an inert atmosphere (e.g., nitrogen or argon) and protected from moisture and air. Store refrigerated at 2-8°C as it may form explosive peroxides. Refer to the Safety Data Sheet for comprehensive handling instructions.
Is this product shipped internationally?
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Yes, Tech Serve Solutions is a specialist global supplier and exporter of fine chemicals, including Lithium diisobutyl-tert-butoxyaluminum hydride solution, and can arrange international shipment.
How can I request a quote or sample?
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To request a quote or sample of Lithium diisobutyl-tert-butoxyaluminum hydride solution, please contact our sales department through the TSS website or by calling our customer service line.
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