Iron(III) perchlorate hydrate
Iron(III) perchlorate hydrate (CAS: 15201-61-3), with the formula Fe(ClO4)3 · xH2O, is a pale violet crystalline solid. It serves as a potent oxidizing agent and a valuable catalyst in various organic syntheses. Its applications span the creation of complex organic molecules like fullerene derivatives and heterocyclic compounds, as well as use in chemical actinometry and the synthesis of conducting polymer nanoparticles.
- IUPAC
- Perchloric acid iron(III) salt hydrate

Catalyst in Organic Synthesis
Iron(III) perchlorate hydrate acts as a catalyst for synthesising diverse organic compounds, including fullerene-fused lactones, α-carbonyl furans, and aryl esters via oxidative esterification.
Chemical Actinometry
This compound is employed as a chemical actinometer. Its photolysis in aqueous solution, in the presence of polyoxometalate, is used for measuring light intensity.
Oxidant for Polymer Synthesis
It functions as an effective oxidant in the chemical polymerization process for synthesizing conducting polymer nanoparticles within ionic liquids.
| Molecular weight | 354.20 (anhydrous basis) |
|---|---|
| Linear formula | Fe(ClO4)3 · xH2O |
| Form | crystalline |
| Colour | pale violet |
| Impurities tested | <0.005% chloride |
| Application | Catalyst for synthesis of: • Fullerene-fused lactones1 • α-Carbonyl furans via one-pot cyclization2• Fullerodioxolanes via heterocyclization3• Dialylated indoles via double alkylation4• Aryl esters via oxidative esterification5Used as chemical actinometer based on photolysis of ferrioxalate in presence of polyoxometalate in aqueous solution6Oxidant for conducting polymer nanoparticles synthesized in ionic liquid by chemical polymerization7 |


Hazard statements
- H272May intensify fire; oxidiser
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P220Keep away from clothing and combustible materials
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 1481 5.1 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | O,Xi |
| Risk statements (R) | 8-36/37/38 |
| Safety statements (S) | 17-26-27 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Iron(III) perchlorate hydrate used for?
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Iron(III) perchlorate hydrate is used as a catalyst in organic synthesis, a chemical actinometer, and an oxidant for the synthesis of conducting polymer nanoparticles.
What are the CAS number and chemical formula for Iron(III) perchlorate hydrate?
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The CAS number is 15201-61-3 and the chemical formula is Fe(ClO4)3 · xH2O.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Iron(III) perchlorate hydrate in crystalline form with less than 0.005% chloride impurity. We do not represent this product as USP, BP, or EP grade.
How should Iron(III) perchlorate hydrate be handled safely?
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Iron(III) perchlorate hydrate is a danger to health and an oxidizer. It can cause severe eye irritation, skin irritation, and respiratory irritation. It also intensifies fire. Handle with appropriate personal protective equipment, including eyeshields, gloves, and respiratory protection. Store away from combustible materials.
Is Iron(III) perchlorate hydrate a controlled substance?
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The provided data does not indicate that Iron(III) perchlorate hydrate is a controlled substance.
How is Iron(III) perchlorate hydrate shipped and exported?
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Iron(III) perchlorate hydrate is classified under UN 1481, hazard class 5.1, with packing group II, indicating it is shipped as an oxidizing solid.
How can I request a sample or quote for Iron(III) perchlorate hydrate?
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Please contact our sales team to request a sample or a quote for Iron(III) perchlorate hydrate.
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