Hexylamine
Hexylamine (CAS: 111-26-2), with the chemical formula CH3(CH2)5NH2 and a molecular weight of 101.19 g/mol, is a primary aliphatic amine. This compound serves as a valuable building block in organic synthesis. Its applications include use as an initiator in polymerization reactions and in surface modification studies via amide and ester formation.
- IUPAC
- 1-Aminohexane
- Synonyms
- 1-Aminohexane

Polymerization Initiator
Hexylamine has been employed as an initiator in the N-carboxyanhydride ring-opening polymerization, contributing to the controlled synthesis of polymers.
Surface Modification
It is utilized in research to modify alkanethiol monolayers on gold surfaces through gas-phase surface reactions, forming amide and ester linkages.
Organic Synthesis Building Block
As a C6 primary amine, Hexylamine is a versatile intermediate in the synthesis of more complex organic molecules and nitrogen-containing compounds.
| Molecular weight | 101.19 |
|---|---|
| Linear formula | CH3(CH2)5NH2 |
| Assay | 99% |
| Boiling point | 131-132 °C(lit.) |
| Density | 0.766 g/mL at 25 °C(lit.) |
| Refractive index | n20/D 1.418(lit.) |
| Application | Hexylamine was used as initiator during the N2 flow-accelerated N-carboxyanhydride ring opening polymerization1. It was also used to study the modification of alkanethlol monolayers via amide and ester formation reaction at gold surface via gas-phase surface reactions2. |
| Melting point | −23 °C(lit.) |




Hazard statements
- H226Flammable liquid and vapour
- H301Toxic if swallowed
- H314Causes severe skin burns and eye damage
- H411Toxic to aquatic life with long-lasting effects
Precautionary statements
- P273Avoid release to the environment
- P280Wear protective gloves, clothing and eye/face protection
- P301IF SWALLOWED
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
|---|---|
| Flash point | 27 °C / 80.6 °F |
| Transport (UN / ADR) | UN 2734 8/PG 1 |
| Water hazard class (WGK, DE) | 1 |
| Hazard codes (EU) | C,N |
| Risk statements (R) | 10-21/22-35-51/53 |
| Safety statements (S) | 26-36/37/39-45-61 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
| Expl Lim | 2.1-9.3 % |
|---|
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Hexylamine used for?
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Hexylamine is used as an initiator in polymerization and for surface modification studies via amide and ester formation. It also serves as a building block in organic synthesis.
What is the CAS number and chemical formula for Hexylamine?
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The CAS number for Hexylamine is 111-26-2, and its chemical formula is CH3(CH2)5NH2.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Hexylamine with a minimum purity of 99%. We do not represent this product as USP, BP, EP, or any other pharmacopoeia grade.
How should Hexylamine be handled safely?
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Hexylamine is a flammable liquid and vapour (H226), corrosive (H314), and toxic if swallowed or in contact with skin (H301 + H311), and toxic to aquatic life with long lasting effects (H411). Handle with appropriate personal protective equipment, including gloves, goggles, and respiratory protection, in a well-ventilated area.
How is Hexylamine packed and shipped?
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Hexylamine is available from Tech Serve Solutions and can be exported globally. Please contact us for specific packaging and shipping details.
How can I request a quote or sample for Hexylamine?
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To request a quote or sample of Hexylamine, please use the contact form on our website or call our sales department.
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