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Hexylamine

CAS 111-26-2CH3(CH2)5NH2Chemical Synthesis

Hexylamine (CAS: 111-26-2), with the chemical formula CH3(CH2)5NH2 and a molecular weight of 101.19 g/mol, is a primary aliphatic amine. This compound serves as a valuable building block in organic synthesis. Its applications include use as an initiator in polymerization reactions and in surface modification studies via amide and ester formation.

IUPAC
1-Aminohexane
Synonyms
1-Aminohexane
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Hexylamine (CH3(CH2)5NH2) — chemical structure, CAS 111-26-2; Chemistry, fine chemical supplied by Tech Serve Solutions
AminesBuilding BlocksChemical SynthesisNitrogen Compounds
01 /Applications

Polymerization Initiator

Hexylamine has been employed as an initiator in the N-carboxyanhydride ring-opening polymerization, contributing to the controlled synthesis of polymers.

Surface Modification

It is utilized in research to modify alkanethiol monolayers on gold surfaces through gas-phase surface reactions, forming amide and ester linkages.

Organic Synthesis Building Block

As a C6 primary amine, Hexylamine is a versatile intermediate in the synthesis of more complex organic molecules and nitrogen-containing compounds.

02 /Properties
Molecular weight101.19
Linear formulaCH3(CH2)5NH2
Assay99%
Boiling point131-132 °C(lit.)
Density0.766 g/mL at 25 °C(lit.)
Refractive indexn20/D 1.418(lit.)
ApplicationHexylamine was used as initiator during the N2 flow-accelerated N-carboxyanhydride ring opening polymerization1. It was also used to study the modification of alkanethlol monolayers via amide and ester formation reaction at gold surface via gas-phase surface reactions2.
Melting point−23 °C(lit.)
03 /Safety & handling
GHS hazard pictogram: Flammable (GHS02)
Flammable
GHS hazard pictogram: Corrosive (GHS05)
Corrosive
GHS hazard pictogram: Toxic (GHS06)
Toxic
GHS hazard pictogram: Environmental hazard (GHS09)
Environmental hazard
Danger

Hazard statements

  • H226Flammable liquid and vapour
  • H301Toxic if swallowed
  • H314Causes severe skin burns and eye damage
  • H411Toxic to aquatic life with long-lasting effects

Precautionary statements

  • P273Avoid release to the environment
  • P280Wear protective gloves, clothing and eye/face protection
  • P301IF SWALLOWED
  • P305IF IN EYES
  • P310Immediately call a POISON CENTER or doctor
Protective equipmentFaceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Flash point27 °C / 80.6 °F
Transport (UN / ADR)UN 2734 8/PG 1
Water hazard class (WGK, DE)1
Hazard codes (EU)C,N
Risk statements (R)10-21/22-35-51/53
Safety statements (S)26-36/37/39-45-61

Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.

04 /Identifiers & registry
CAS number
111-26-2
MDL number
MFCD00008240
PubChem substance
24853140
Beilstein registry
1731298
05 /Additional specifications
Expl Lim2.1-9.3 %
06 /Quality & supply

Documentation

Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.

Supply & logistics

Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.

07 /Frequently asked questions

What is Hexylamine used for?

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Hexylamine is used as an initiator in polymerization and for surface modification studies via amide and ester formation. It also serves as a building block in organic synthesis.

What is the CAS number and chemical formula for Hexylamine?

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The CAS number for Hexylamine is 111-26-2, and its chemical formula is CH3(CH2)5NH2.

What grade and purity does Tech Serve Solutions supply?

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Tech Serve Solutions supplies Hexylamine with a minimum purity of 99%. We do not represent this product as USP, BP, EP, or any other pharmacopoeia grade.

How should Hexylamine be handled safely?

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Hexylamine is a flammable liquid and vapour (H226), corrosive (H314), and toxic if swallowed or in contact with skin (H301 + H311), and toxic to aquatic life with long lasting effects (H411). Handle with appropriate personal protective equipment, including gloves, goggles, and respiratory protection, in a well-ventilated area.

How is Hexylamine packed and shipped?

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Hexylamine is available from Tech Serve Solutions and can be exported globally. Please contact us for specific packaging and shipping details.

How can I request a quote or sample for Hexylamine?

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To request a quote or sample of Hexylamine, please use the contact form on our website or call our sales department.

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