Hafnium(IV) oxychloride hydrate
Hafnium(IV) oxychloride hydrate (CAS: 15461-28-6) is a crystalline hafnium salt with the linear formula HfOCl₂ · xH₂O. Its anhydrous molar mass is 265.40. This high-purity material, assayed at 99.99% on a trace metals basis (excluding zirconium), serves as a crucial starting material in the synthesis of advanced phosphors for X-ray applications, specifically HfGeO₄ and HfGeO₄:Ti.

Phosphor Synthesis
Utilised as a precursor in the production of hafnium germanate phosphors, such as HfGeO₄ and HfGeO₄:Ti. These materials are essential for X-ray imaging applications due to their luminescent properties.
Materials Science Research
Serves as a valuable research chemical for exploring novel hafnium-based materials. Its defined purity makes it suitable for precise material characterisation and development.
Ceramic Precursor
Can be employed in the development of specialised ceramics. Hafnium compounds are known for their high melting points and chemical stability, making them useful in advanced ceramic formulations.
| Molecular weight | 265.40 (anhydrous basis) |
|---|---|
| Linear formula | HfOCl2 · xH2O |
| Assay | 99.99% trace metals basis (purity excludes zirconium) |
| Form | crystalline |
| Application | Starting material for HfGeO4 and HfGeO4:Ti, both used in x-ray phosphors.1 |


Hazard statements
- H302Harmful if swallowed
- H314Causes severe skin burns and eye damage
Precautionary statements
- P280Wear protective gloves, clothing and eye/face protection
- P305IF IN EYES
- P310Immediately call a POISON CENTER or doctor
| Protective equipment | Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges |
|---|---|
| Transport (UN / ADR) | UN 3260 8 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | C |
| Risk statements (R) | 20/21/22-34 |
| Safety statements (S) | 26-27-28-36/37/39-45 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Hafnium(IV) oxychloride hydrate used for?
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Hafnium(IV) oxychloride hydrate is primarily used as a starting material for synthesising HfGeO₄ and HfGeO₄:Ti, which are employed in X-ray phosphors. It also finds applications in materials science and ceramic research.
What is the CAS number and formula for Hafnium(IV) oxychloride hydrate?
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The CAS number is 15461-28-6, and its linear formula is HfOCl₂ · xH₂O.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Hafnium(IV) oxychloride hydrate with an assay of 99.99% on a trace metals basis (excluding zirconium). This is a technical/research grade; TSS does not represent it as USP, BP, or EP.
How should Hafnium(IV) oxychloride hydrate be handled safely?
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This compound is corrosive and harmful if swallowed, inhaled, or in contact with skin. Handle with appropriate personal protective equipment, including eyeshields, gloves, and a suitable respirator. Ensure adequate ventilation and avoid dust formation. Refer to the Safety Data Sheet for full details.
How is Hafnium(IV) oxychloride hydrate packed, shipped, and exported?
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Hafnium(IV) oxychloride hydrate is packed in compliance with transport regulations for hazardous materials (UN 3260, Class 8, PG II). We export globally, adhering to all international shipping and customs requirements for chemical substances.
How can I request a quote or sample?
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To request a quote or a sample of Hafnium(IV) oxychloride hydrate, please contact our sales team via the website or email, providing your specific requirements and shipping details.
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