Ferrocenium hexafluorophosphate
Ferrocenium hexafluorophosphate (CAS: 11077-24-0, C10H10F6FeP) is an organometallic compound with a molecular weight of 331.00. This stable, orange solid is recognized for its utility in catalysis, particularly in asymmetric epoxidation and carbonylations. Its unique electronic properties also lend themselves to applications in chemical synthesis and inorganic chemistry, making it a valuable reagent for advanced research and development in academic and industrial settings.

Asymmetric Epoxidation Catalysis
The ferrocenium cation serves as a precursor for catalysts employed in the enantioselective epoxidation of olefins, enabling the synthesis of chiral epoxides.
Carbonylation Reactions
It has been utilised in the preparation of catalysts for the carbonylation of nitroaromatic compounds, a key transformation in organic synthesis.
Isomerization Studies
Ferrocenium hexafluorophosphate has been applied in catalytic systems for the isomerization of strained dienes, contributing to mechanistic investigations.
Chemical Synthesis Reagent
Its distinct redox properties make it a useful reagent in various organic and organometallic synthetic methodologies.
| Molecular weight | 331.00 |
|---|---|
| Empirical formula | C10H10F6FeP |
| Assay | 97% |
| Application | The ferrocenium cation has been used to prepare catalysts for the asymmetric epoxidation of olefins,1 carbonylations of nitroaromatics,2 and the isomerization of a strained diene.3 |

Hazard statements
- H315Causes skin irritation
- H319Causes serious eye irritation
- H335May cause respiratory irritation
Precautionary statements
- P261Avoid breathing dust, fume, gas or vapours
- P305IF IN EYES
| Protective equipment | dust mask type N95 (US), Eyeshields, Gloves |
|---|---|
| Transport (UN / ADR) | UN 3261 8 / PGII |
| Water hazard class (WGK, DE) | 3 |
| Hazard codes (EU) | Xi |
| Risk statements (R) | 36/37/38 |
| Safety statements (S) | 26-36 |
Hazard information is provided for guidance. Always consult the product Safety Data Sheet (SDS), available on request, before handling.
Documentation
Every batch ships with a Certificate of Analysis covering assay, identity and purity; the grade is confirmed against your enquiry. Safety Data Sheets and technical data sheets are available on request.
Supply & logistics
Samples for technical evaluation; bulk MOQ by grade and packaging. In-stock material ships in 7–10 working days, worldwide, with full export documentation.
What is Ferrocenium hexafluorophosphate used for?
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Ferrocenium hexafluorophosphate is primarily used as a precursor in catalysis for asymmetric epoxidation of olefins, carbonylation of nitroaromatics, and isomerization of dienes. It also finds application in chemical synthesis and inorganic chemistry.
What is the CAS number and chemical formula?
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The CAS number is 11077-24-0 and the chemical formula is C10H10F6FeP.
What grade and purity does Tech Serve Solutions supply?
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Tech Serve Solutions supplies Ferrocenium hexafluorophosphate with an assay of 97%. This product is not classified as USP, BP, or EP grade.
How should Ferrocenium hexafluorophosphate be handled safely?
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Handle with appropriate personal protective equipment, including a dust mask type N95 (US), eyeshields, and gloves. Avoid breathing dust. Ensure adequate ventilation. This compound is classified as a Warning with hazards H315 (Causes skin irritation), H319 (Causes serious eye irritation), and H335 (May cause respiratory irritation).
Is Ferrocenium hexafluorophosphate suitable for export?
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Yes, Ferrocenium hexafluorophosphate is available for export globally. It is classified under UN 3261, 8 / PGII for transportation.
How can I request a quote or sample?
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To request a quote or a sample, please contact the Tech Serve Solutions sales team through our website or by calling our customer service line.
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